UMPOLUNG

作品数：13被引量：5H指数：1
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相关机构：华中师范大学更多>>
相关期刊：《Science Bulletin》《Chinese Journal of Catalysis》《Chinese Journal of Chemistry》《Organic Chemistry Frontiers》更多>>
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Nickel-catalyzed umpolung C-S radical reductive cross coupling of S-(trifluoromethyl)arylsulfonothioates with alkyl halides
《Chinese Chemical Letters》2023年第11期137-142,共6页Yu-Zhong Yang Gui-Fen Lv Ming Hu Yang Li Jin-Heng Li 
the National Natural Science Foundation of China(No.22271245);the Jiangxi Province Science and Technology Project(Nos.20212AEI91002 and 20202ACBL213002);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2021ZD01)for financial support.
A new cooperative nickel reductive catalysis and N,N-dimethylformamide-mediated strategy for umpolung C–S radical reductive cross coupling of S-(trifluoromethyl)arylsulfonothioates with alkyl halides to produce alkyl...
关键词：Nickel RADICAL Reductive cross coupling S-(Trifluoromethyl)arylsulfonothioates Alkyl halides Alkyl aryl thioethers 
Electrochemical Umpolung Enabled Radical-Radical Cross-Coupling Between Electron-Deficient Methylarenes and Aldehydes被引量：1
《CCS Chemistry》2023年第9期1973-1981,共9页Fei Lian Kun Xu Chengchu Zeng 
the National Natural Science Foundation of China(grant nos.22271009 and 22171015);Beijing Natural Science Foundation(grant no.2222003);Beijing Municipal Education Committee Project(grant nos.KZ202110005003 and KM202110005006).
The electrochemical utilization of electron-deficient methylarenes for radical-radical cross-couplings remains very rare.Enabled by an umpolung strategy,the unprecedented electrochemical cross-coupling of electron-def...
关键词：paired electrolysis ketyl radical UMPOLUNG radical-radical cross-coupling methylarene ALDEHYDE 
Predictable site-selective radical fluorination of tertiary ethers被引量：2
《Science China Chemistry》2020年第2期187-191,共5页Junyang Ma Wentao Xu Jin Xie 
supported by the National Natural Science Foundation of China(21971108,21702098);the Natural Science Foundation of Jiangsu Province(BK20190006);Fundamental Research Funds for the Central Universities(020514380176);“Jiangsu Six Peak Talent Project”;“1000-Youth Talents Plan’’;start-up funds from Nanjing University;supported by the Scientific Research Foundation of Graduate School of Nanjing University(2018CL05)
In this communication,we disclose the first example of metal-free and site-selective radical fluorination of readily available tertiary alkyl ethers,enabled by synergistic photocatalysis and organocatalysis.This catal...
关键词：cooperative catalysis C–O bond activation radical fluorination polarity-matching effect UMPOLUNG 
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