Rational design of efficient pH-universal hydrogen evolution reaction catalysts to enable large-scale hydrogen production via electrochemical water splitting is of great significance,yet a challenging task.Herein,Ru a...
Inspired by the anti-pancreatic promising results of our novel aminated cyclopropylmethylphosphonate compounds, an in vitro anti-prostate cancer activity exploration of these compounds was carried out on human prostat...
Buoyed by the extensive research on the wide-range biological activities of aminophosphonates, a novel class of aminated (cyclopropylmethyl)phosphor-nates compounds was synthesized from diethyl ((1-(3-chloropropyl)cyc...
supported by the National Natural Science Foundation of China (22071183);the Science and Technology Commission of Shanghai Municipality (19DZ2271500)。
Chiral phosphine-containing skeletons play a pivotal role in bioactive natural products, pharmaceuticals, chiral catalysts, and ligands. Despite considerable progress has been made in the synthesis of chiral phosphoru...
the National Natural Science Foundation of China (No. 52000102);the Natural Science Foundation of Jiangsu Province (No. BK20190689) for offering financial support to this research。
Traditional treatment processes cannot completely remove phosphonates in circulating cooling water by one-step method. Herein, we designed peroxymonosulfate/UV irradiation/hydrated zirconium oxide(PMS/UV/HZO) coupling...
the National Natural Science Foundation of China(Nos.21671098,21731003);the Fundamental Research Funds for the Central Universities(Nos.14380151,14380206)is acknowledged。
The thermal decomposition of Ag NO_(3)is known to produce metallic Ag,but single-atomic dispersion is hard to achieve instead of the aggregation state of nanoparticles.Herein,we develop an efficient approach to therma...
supports from the National Natural Science Foundation of China (No. 21761132021);German Research Foundation (No. RO362/74–1);Qin Lan project from Jiangsu Province for JLH is also acknowledged
An efficient chlorination reaction of in situ generated(β-diazo-α,α-difluoroethyl)phosphonates has been achieved with hydrochloric acid as a chlorine source under mild and operationally convenient conditions.The re...
supported by the National Natural Science Foundation of China (Nos.21772142,21901181 and 21961142015);the National Key Research and Development Program of China (No.2019YFA0905100);Tianjin Municipal Science & Technology Commission (No.19JCQNJC04700);the CNRS in France。
Three bench-stable difluoromethylene phosphonate hydrazones were prepared from simple diethyl(difluoromethyl)phosphonate within two steps in good yields. The [3 + 2] cycloaddition reaction of these diazo precursors wi...
the National Natural Science Foundation of China(No.21625203 and 21871126);the Jiangxi Province Science and Technology Project(No.20182BCB22007,20202ACB203002,and 20202BAB213004);the Talent Induction Program for Youth Innovation Teams in Colleges and Universities of Shandong Province;the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2021ZD01)for financial support.
A copper-catalyzed oxidative intermolecular phosphonoheteroarylation of alkenes with phosphonates and nucleophilic N-heteroarenes(such as indoles and pyrroles)involving P-H/C-H functionalization for the synthesis of h...
Supported financially by Suqian Sci&Tech Program(No.K201911);the second batch of university-level scientific research platform of Suqian University(No.2021pt04)。
Two novel copper carboxyly-phosphonates,namely,Cu2.5(5-pnc)(SO_(4))0.5(OH)(H_(2)O)0.5(1)and Cu0.5(5-pncH2)(H2O)1.5(2)(5-pncH3=5-phosphono-1-naphthalenecarboxylic acid),have been synthesized and characterized by X-ray ...