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supported by the Project of the National Natural Science Foundation of China(Grant Nos.20776003,20576005);the Key Project of Natural Science Foundation of Beijing(No.2061001).
By using mixed-solvents method,five kinds of p-substituted tetraphenylporphyrin compounds[T(p-R)PPH_(2),R=NO_(2),Cl,CH_(3),OCH_(3),OH]were synthesized by the condensation of p-substituted benzaldehyde with pyrrole in ...
supported by the Key Project of Natural Science Foundation of Beijing(Grant No.2061001).
The catalysis of chloridized metalloporphyrins in the oxidation of cyclohexane to adipic acid was systemati-cally investigated.The turnover numbers(TON)data of 19 catalysts were obtained experimentally under optimal r...