METALLOPORPHYRIN

作品数：58被引量：80H指数：4
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相关领域：理学更多>>
相关作者：申亮亮李培荣史林启更多>>
相关机构：首都师范大学南开大学更多>>
相关期刊：《Science China Chemistry》《Journal of Chemistry and Chemical Engineering》《Open Journal of Inorganic Chemistry》《Chinese Journal of Structural Chemistry》更多>>
相关基金：国家自然科学基金广东省自然科学基金国家高技术研究发展计划北京市自然科学基金更多>>
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Inspired by natural chloroplasts to construct Z-scheme heterojunction with efficient charge transfer mechanism for boosting photocatalytic carbon dioxide reduction
《分子科学学报》2024年第5期411-420,共10页LIU Zixuan ZHOU Xiang SONG Tingting YAO Ruiqi ZHAO Zhao LANG Zhongling LI Yingqi TAN Huaqiao WANG Yonghui LI Yangguang 
supported by the National Natural Science Foundation of China(22071020,22171041,22379024,22205034);the Natural Science Foundation of Jilin Province Science and Technology Department(20230508094RC and 20240101178JC);the Fundamental Research Funds for Central Universities(2412022QD012)
To alleviate the growing serious ecological threats brought by carbon-based fuels,it is a promising approach to construct a Z-scheme heterojunction via simulating the photosynthetic mechanism for solar-driven CO_(2)re...
关键词：biomimetic Z-scheme heterojunction polyoxometalates metalloporphyrin-like Co-CN nanosheets electrostatic self-assembly photocatalytic CO_(2)reduction 
Photo-Responsive Carbon Capture over Metalloporphyrin-C_(60) Metal-Organic Frameworks via Charge-Transfer
《Research》2024年第3期233-241,共9页Shi-Chao Qi Zhen Sun Zhi-Hui Yang Yun-Jie Zhao Jia-Xin Li Xiao-Qin Liu Lin-Bing Sun 
the National Natural Science Foundation of China(22178163,22125804,and 22078155).
Great efforts have been devoted to the study of photo-responsive adsorption,but its current methodology largely depends on the well-defined photochromic units and their photo-driven molecular deformation.Here,a method...
关键词：PORPHYRIN adsorption EXCITED 
A trans-ortho asymmetrically di-strapped metalloporphyrin integrating three key structural features of ligand in heme
《Chinese Chemical Letters》2023年第10期140-145,共6页Qiuhua Liu Junhao Gao Yusheng Zhang Xin Liu Xi Zhang Qin Lin Wennan Zeng Zaichun Zhou 
supported by the Institute of Elemento-organic Chemistry,Nankai University and the Scientific Research Fund of Hunan Provincial Education Department(No.20A195);Hunan Provincial Natural Science Foundation of China(No.2020JJ4292);the Science and Technology innovation Program of Hunan Province(No.2021RC5028).
Heme responsible for the dioxygen fixation,transport and conversion is a metalloporphyrin complex highly dependent on its diverse geometry of ligand.In this work,a trans-ortho-di-strapped zinc porphyrin with dome-like...
关键词：Supramolecular effect Heme analog Pocket effect Axial ligation Ring distortion 
Dual-functional photocatalysis boosted by electrostatic assembly of porphyrinic metal-organic framework heterojunction composites with CdS quantum dots被引量：4
《Chinese Chemical Letters》2023年第9期165-170,共6页Zhiyao Chen Sihong Li Qijie Mo Li Zhang Cheng-Yong Su 
support from the National Natural Science Foundation of China(Nos.21773314,21821003 and 21890382);the Guangdong Natural Science Funds for Distinguished Young Scholar(No.2019B151502017)。
Photocatalytic dual-functional reaction under visible light irradiation represents a sustainable development strategy.In detail,H2production coupled with benzylamine oxidation can remarkably lower the cost by replacin...
关键词：Metal-organic framework composites Electrostatic self-assembly Dual-functional photocatalysis CdS quantum dots METALLOPORPHYRIN 
Ultrathin two-dimensional porphyrinic metal-organic framework nanosheets induced by the axial aryl substituent被引量：3
《Chinese Chemical Letters》2023年第7期117-121,共5页Jurong Dong Yufei Wang Yu-Lin Lu Li Zhang 
support from the National Natural Science Foundation of China (Nos. 21773314, 21821003 and 21890382);the Guangdong Natural Science Funds for Distinguished Young Scholar (No. 2019B151502017)。
Ultrathin two-dimensional metal-organic framework nanosheets have emerged as a promising kind of heterogeneous catalysts. Herein, we report a new kind of 2D porphyrinic metal-organic framework nanosheets of Rh2-PCN-22...
关键词：METALLOPORPHYRIN Axial aryl substituent 2D MOF nanosheets CO_(2)transformation Heterogeneous catalysis 
Single-atom catalysts based on two-dimensional metalloporphyrin monolayers for ammonia synthesis under ambient conditions被引量：4
《Nano Research》2022年第5期4039-4047,共9页Chun-Xiang Huang Sheng-Yao Lv Cong Li Bin Peng Guoliang Li Li-Ming Yang 
C.-X.H.,S.-Y.L.,C.L.,and L.-M.Y.gratefully acknowledge support from the National Natural Science Foundation of China(Nos.22073033,21873032,21673087,and 21903032);the startup fund(Nos.2006013118 and 3004013105)from Huazhong University of Science and Technology,the Fundamental Research Funds for the Central Universities(No.2019kfyRCPY116);the Innovation and Talent Recruitment Base of New Energy Chemistry and Device(B21003);C.-X.H.,S.-Y.L.,and G.-L.L.gratefully acknowledge support from Guangdong Basic and Applied Basic Research Foundation(No.2021A1515010382).
We systematically investigated the catalytic performance of 3d,4d,and 5d transition metals anchored onto two-dimensional extended porphyrin(PP)substrates as nitrogen reduction reaction(NRR)electrocatalysts,employing d...
关键词：electrocatalytic nitrogen reduction reaction two-dimensional(2D)extended metalloporphyrin(MPP)monolayer singleatom catalyst two-dimensional materials high-throughput screening first-principles calculations 
Aluminum Porphyrin Complex Mediated Auto-Tandem Catalysis for One-Pot Synthesis of Block Copolymers
《CCS Chemistry》2022年第1期122-131,共10页Yajun Zhao Shuaishuai Zhu Xiaojing Li Xiaoyu Zhao Jing Xu Bijin Xiong Yong Wang Xingping Zhou Xiaolin Xie 
Financial support from National Key R&D Plan(no.2016YFB0302400);NSFC(no.21604027)of China;the Fundamental Research Funds for the Central Universities(HUST:2019JYCXJJ015).
Auto-tandem catalysis that uses a single catalyst to bridge and discriminate different catalytic cycles in a one-pot process is highly desirable for obtaining a high degree of structural complexity;however,it is a gre...
关键词：auto-tandem catalysis PET-RAFT polymerization ring-opening copolymerization block copolymer METALLOPORPHYRIN 
Metalloporphyrin-based covalent organic frameworks composed of the electron donor-acceptor dyads for visible-light-driven selective CO2 reduction被引量：5
《Science China Chemistry》2020年第9期1289-1294,共6页Haowei Lv Rongjian Sa Pengyue Li Daqiang Yuan Xinchen Wang Ruihu Wang 
the National Natural Science Foundation of China(21673241,21975259);STS Program of Chinese Academy of Science(KF-STS-QYZX-068);Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000)。
The visible-light-driven photocatalytic CO2 reduction with high efficiency is highly desirable but challenging.Herein,we present porphyrin-tetraphenylethene-based covalent organic frameworks(MP-TPE-COF,where M=H2,Co a...
关键词：covalent organic frameworks PHOTOCATALYSIS porous materials CO2reduction METALLOPORPHYRIN 
Amino-metalloporphyrin polymers derived Fe single atom catalysts for highly efficient oxygen reduction reaction被引量：2
《Science China Chemistry》2020年第6期810-817,共8页Qian He Yuying Meng Hao Zhang Ying Zhang Qingdi Sun Tao Gan Huajian Xiao Xiaohui He Hongbing Ji 
supported by the National Natural Science Foundation of China(21938001、21606260、21576302、21376278、21425627、21701199);the National Natural Science Foundation of ChinaSINOPEC Joint Fund(U1663220);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01C102);the Natural Science Foundation of Guang-dong Province(2015A030313104);the Fundamental Research Funds for the Central Universities of Sun Yat-sen University(15lgjc33、19lgpy129)。
Recently,nitrogen-doped porous carbon supported single atom catalysts(SACs)have become one of the most promising alternatives to precious metal catalysts in oxygen reduction reaction(ORR)due to their outstanding perfo...
关键词：single atom catalysts PORPHYRIN precursor-dilution oxygen reduction reaction active site 
A DFT and TD-DFT study on electronic structures and UV-spectra properties of octaethyl-porphyrin with different central metals(Ni, V, Cu, Co)被引量：7
《Chinese Journal of Chemical Engineering》2020年第2期532-540,共9页XiaoqinWang Shiyi Li Liang Zhao Chunming Xu Jinsen Gao 
the supports from the National Natural Science Foundation of China(21822810,21476260,and 21838011).
In this work,the octaethyl-porphyrins with different central metals(M-OEP,M=Ni,VO,Cu,Co)were used to investigate the ground-state molecular structure,electron distribution and UV-spectra properties on molecular level ...
关键词：Metallic impurity METALLOPORPHYRIN ASPHALTENES Quantum chemistry UV–vis spectrum 
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