HETEROPOLYTUNGSTATE

作品数:11被引量:16H指数:2
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相关领域:理学更多>>
相关期刊:《Chemical Research in Chinese Universities》《Chinese Journal of Structural Chemistry》《Chinese Journal of Chemistry》《Science China Chemistry》更多>>
相关基金:国家自然科学基金国家高技术研究发展计划福建省教委科研基金福建省自然科学基金更多>>
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Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy
《Chemical Research in Chinese Universities》2020年第6期1161-1167,共7页ZHANG Wenqi LIN Zhengguo CHI Yingnan HONG Jie YAN Li HU Changwen 
Supported by the National Natural Science Foundation of China(Nos.21871026,21671019,21701010).
Three novel scandium-containing heteropolytungstates[Sc3(H2O)3NO(PW9O34)2]^10(1a)Scs(H2O)2(GeW6O34)2(GeW6O26)2]^12(2a)and[Sc11(W6O10)2(OH)2(H2O)16(BiW9O33)6]^27(3a)were synthesized by reactions of Sclllions with trila...
关键词:SCANDIUM HETEROPOLYTUNGSTATE BUILDING-BLOCK Crystal structure 
Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst被引量:5
《Chinese Chemical Letters》2007年第8期936-938,共3页Zhi Huan Weng Jin Yan Wang Xi Gao Jian 
A series of heteropolytungstates has been synthesized and utilized as catalysts to catalyze oxidation of benzyl alcohol with aqueous hydrogen peroxide. The results indicated that three of these catalysts showed the pr...
关键词:HETEROPOLYTUNGSTATE Reaction-controlled phase-transfer Benzyl alcohol BENZALDEHYDE Hydrogen peroxide 
A new chain-like heteropolytungstate formed by Keggin cluster units:Synthesis and structure of[H2bpy]3[SiMnW(11)O(39)].1.25H2O被引量:2
《Chinese Chemical Letters》2007年第1期81-84,共4页Jing Xin Meng Ying Ma Xin Xin Xu Yang Guang Li En Bo Wang 
This work was supported by the National Natural Science Foundation of China(20371011).
A new heteropolytungstate, [H2bpy]3[SiMnW11O39]· 1.25H2O (1), has been prepared under mild hydrothermal conditions and structurally characterized by single crystal X-ray diffraction. It is the first characterized c...
关键词:HETEROPOLYTUNGSTATE Keggin clusters Zigzag chain 
Synthesis, Crystal Structure and Magnetic Property of Sanwich-Type Heteropolyoxometalate Na_9[{Na(H_2O)_2}_3{Cu(H_2O)}_3(BiW_9O_(33))_2]·42H_2O
《Chinese Journal of Chemistry》2004年第2期159-161,共3页薛岗林 王虎林 谢志海 史启祯 王继武 王大奇 
Project supported by Visiting Scholar Foundation of Key Lab in Chinese Universities and the Education Commission of Shaanxi Province (No. 03JK077).
The heteropolytungstate Na9[{Na(H2O)2}3{Cu(H2O)}3(BiW9O33)2]?2H2O is obtained by the reaction of Na2WO4·2H2O, Bi(NO3)3·5H2O with CuCl2·2H2O at pH≈6. The structure and chemical composition are de-termined by X-ray ...
关键词:HETEROPOLYTUNGSTATE crystal structure copper BISMUTH magnetic property 
Synthesis and luminescent properties of Eu^(3+)-doped Na_(24)As_2W_(22)O_(83)
《Rare Metals》2003年第2期95-97,共3页YANGShuijin YUANLiangjie SUNJutang 
This project is financially supported by the National Natural Science Foundation of China (No. 29971024) ; the Natural Science Foundation of Hubei Education Committee (No. 2002A00008)
The Eu^(3+)-doped Na^(24)As_2W_(22)O_83 phosphor has been prepared by solidstare reaction from Na_3AsO_4.12H_2O, Na_2WO_4.2H_2O and WO_3, and characterized by elementalanalysis, infrared spectroscopy and powder X-ray ...
关键词:HETEROPOLYTUNGSTATE europium ion crystal structure SYNTHESIS LUMINESCENCE 
Novel large heteropolymetalate complexes formed from Ni(II) and cryptate [As_4W_(40)O_(140)]^(28-)——Synthesis and structure characterization
《Science China Chemistry》2003年第1期104-111,共8页薛岗林 刘斌 王文亮 王继武 王大奇 
This work was supported by the Foundation of Shaanxi Key Laboratory of Chemical Reaction Engineering.
The heteropolytungstate(NH_4)_(20)[Na_2(H_2O)_2Ni(H_2O)_5{Ni(H_2O)}_2As_4W_(40)O_(140)] · 61H_2O is obtained by thereaction of Na_(27)[NaAs_4W_(40)O_(140)] · 60H_2O with NiCl_2 · 6H_2O and NH_4Cl in pH ≈ 4.0. Thes...
关键词:HETEROPOLYTUNGSTATE crystal structure tungsten nickel ARSENIC 
Synthesis and Crystal Structure of Na_(10)[LaSiW_(11)O_(39)(H_2O)_4]_2·22H_2O被引量:2
《Chinese Journal of Structural Chemistry》2001年第6期451-454,共4页赵士龙 张汉辉  
the foundation of NSF of Fujian Province (2000F002);the foundation of Education Committee of Fujian Province (JA00137).
The complex Na10[LaSiW11O39(H2O)4]2?2H2O was synthesized and crystallized in monoclinic,space group P21/n with cell parameters: a=17.9786(9), b=23.5940(2), c=13.1289(8), β=90.141(2)°, V=5569.1(6)3, Mr=6336.60, Z=2, ...
关键词:SYNTHESIS crystal structure LANTHANIDE HETEROPOLYTUNGSTATE 
A Novel Dimer──Heteropolytungstate with a Vanadium Atom as the Centre ──Synthesis and Structural Characterization of (H_3O)_4[VW_(12)O_(40)Na(H_2O)_4]_2被引量:2
《Chemical Research in Chinese Universities》2000年第3期198-202,共5页LIU Zong-rui XU Lin WANG En-bo PENG Jun HU Chang-wen XING Yan LIN Yong-hua JIA Heng-qing 
Supported financially by the Key laboratory of Inorganic Hydrothermal Synthesis of Jilin University
A novel dimer tungstovanadate, (H 3O) 4[VW 12 O 40 Na(H 2O) 4] 2, was hydrothermally synthesized and structurally characterized by single crystal X ray diffraction, IR spectra, TGA DSC thermal analysis...
关键词:SYNTHESIS Crystal structure Tungstovanadate 
Synthesis and Luminescent Properties of Eu^(3+)-Doped Na_(24)P_2W_(22)O_(83)被引量:5
《Chinese Chemical Letters》1998年第10期911-912,共2页Shui Jin YANG Ju Tang SUN and Zi Bin QIN(Depaltment of Chemistry, Hubei Normal University, Huangshi, 435002 Department of Chemistry, Wuhan University, Wuhan 430072) 
The Eu3+-doped Na24P2W22O83 has been prepared by solid state reaction, and characterized by element analysis, infrared spectroscopy, powder X-ray diffractometry. The emission and excitation spectra were measured. The ...
关键词:HETEROPOLYTUNGSTATE EUROPIUM crystal structure PHOSPHOR 
Preparation and ^(183)W NMR Investigation of Iridium-containing Dawson Derivative
《Chemical Research in Chinese Universities》1996年第4期393-396,共4页LIU Hui-zhang YUE Bin LI Ming-xing CHEN Zhi-jiang JIN Song-lin and XIE Gao-yang(Department of Chemistry,Fudan University,Shanghai,200433) 
Preparationand;WNMRInvestigationofIridium-containingDawsonDerivativeLIUHui-zhang;YUEBin;LIMing-xing;CHENZhi-...
关键词:s:Iridium-substituted heteropolytungstate Partial electron delocalization Dawson derivative 
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