MIXED-VALENCE

作品数：45被引量：19H指数：2
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A mixed-valence polyoxometalate-based 3D inorganic framework cathode material for high-efficiency rechargeable AZIBs
《Rare Metals》2024年第8期3677-3691,共15页Qing Han Hao-Ran Xiao Tao Zhou Bing-Chuan Li Liu Yang Ling-Ling Xie Xue-Jing Qiu Xian-Yong Wu Li-Min Zhu Xiao-Yu Cao 
financially supported by the National Natural Science Foundation of China(Nos.52071132,52261135632 and U21A20284);Zhongyuan Thousand People PlanThe Zhongyuan Youth Talent Support Program(in Science and Technology),China(No.ZYQR201810139);the Natural Science Foundation of Henan,China(Nos.232300421080 and 222300420138);the Science and Technology Project of Henan Province,China(Nos.232102241038 and 232102241004);the Key Scientific Research Programs in Universities of Henan Province,China-Special Projects for Basic Research(No.23ZX008);the Innovative Funds Plan of Henan University of Technology,China(No.2020ZKCJ04);the Ph.D.Programs Foundation of HenanUniversity of Technology,China(No.2021BS0027);the Doctoral Education Fund of Henan University of Engineering,China(No.DKJ2019004)。
The global trend towards new energy storage systems has stimulated the development of electrochemical energy storage technologies.Among these technologies,rechargeable aqueous zinc-ion batteries(AZIBs)have attracted c...
关键词：CATHODE POLYOXOMETALATE 3D inorganic framework Zinc-ion batteries Energy storage mechanism 
Carbon nanotube-supported mixed-valence Mn_(3)O_(4) electrodes for high-performance lithium-oxygen batteries
《ChemPhysMater》2024年第1期94-102,共9页Yuting Zhu Jing Gao Zhongxiao Wang Rui Sun Longwei Yin Chengxiang Wang Zhiwei Zhang 
the Nature Science Foun-dation of Shandong Province(Grant No:ZR2019BEM019);Future Plans of Young Scholars at Shandong University.
Lithium-oxygen batteries(LOBs)have extensive applications because of their ultra-high energy densities.However,the practical application of LOBs is limited by several factors,such as a high overpotential,poor cycle st...
关键词：Mixed-valence states Carbon nanotube Electrode reaction kinetics Lithium–oxygen batteries 
Alternative lead-free mixed-valence double perovskites for high-efficiency photovoltaic applications
《Journal of Energy Chemistry》2023年第9期347-353,共7页Wenbo Li Yuheng Li Zilong Zhang Peng Gao 
the National Natural Science Foundation of China (22175180, 21975260)。
Lead-based organic-inorganic hybrid perovskites have exhibited great potential in photovoltaics,achieving power conversion efficiencies(PCEs) exceeding 25%.However,the toxicity of lead and the instability of these mat...
关键词：Mixed valence double perovskite Theoretical calculation Electronic configuration Photovoltaic performance 
Ultrahigh electrochemical performance in mixed-valence Cu_(1.85)Sebased anode for supercapacitors被引量：1
《Journal of Materiomics》2023年第1期62-71,共10页Zhipeng Li Yi Niu Xinrui He Yalin Hu Fu Li Xing Chen Zhirong Wang Jing Jiang Chao Wang 
The work is funded by the subproject of the National Key Research and Development Program of China(2017YFC0602102);the Department of Science and Technology of Sichuan Province(2021JDTD0030);the National Natural Science Foundation of China(No.U20A20213,61727818,51874184);the Chengdu Science and Technology Project(2020-GH02-0065-HZ)。
Mixed-valence is an effective way to achieve high electrochemical performance of anodes for supercapacitor.However,inordinate mixed valence with more structural defects leads to structural instability.The development ...
关键词：SUPERCAPACITOR Mixed-valence Cu1.85Se/MWCNTs ANODE Ultrahigh specific capacity 
Evidence for charge and spin density waves in single crystals of La_(3)Ni_(2)O_(7) and La_(3)Ni_(2)O_(6)被引量：6
《Science China(Physics,Mechanics & Astronomy)》2023年第1期164-170,共7页Zengjia Liu Hualei Sun Mengwu Huo Xiaoyan Ma Yi Ji Enkui Yi Lisi Li Hui Liu Jia Yu Ziyou Zhang Zhiqiang Chen Feixiang Liang Hongliang Dong Hanjie Guo Dingyong Zhong Bing Shen Shiliang Li Meng Wang 
supported by the National Natural Science Foundation of China(Grant Nos.12174454,11904414,11904416,and U2130101);the Guangdong Basic and Applied Basic Research Foundation(Grant No.2021B1515120015);the Guangzhou Basic and Applied Basic Research Foundation(Grant No.202201011123);the National Key Research and Development Program of China(Grant Nos.2019YFA0705702,2020YFA0406003,2021YFA1400401,and 2021YFA0718900)。
Charge and spin orders are intimately related to superconductivity in copper oxide superconductors.Elucidation of the competing orders in various nickel oxide compounds is crucial,given the fact that superconductivity...
关键词：charge-density-wave systems spin-density waves mixed-valence solids SUPERLATTICES crystal growth 
Breaking the linear correlations for enhanced electrochemical nitrogen reduction by carbon-encapsulated mixed-valence Fe_(7)(PO_(4))_(6)被引量：2
《Journal of Energy Chemistry》2022年第8期182-187,I0006,共7页Lehui Ma Fanfan Xu Linlin Zhang Zhongfen Nie Kai Xia Mingxia Guo Mingzhu Li Xin Ding 
supported by the National Natural Science Foundation of China(21908120 and 22109078);the Youth Innovation Team Project of Shandong Provincial Education Department(2019KJC023)。
Electrochemical nitrogen reduction(NRR)is deemed as a consummate answer for the traditional Haber–Bosch technology.Breaking the linear correlations between adsorption and transition-state energies of intermediates is...
关键词：N2 reduction reaction(NRR) MIXED-VALENCE Linear correlations Nitrogen fixation N_(2)activation 
Thermally Induced Reversible Metal-to-Metal Charge Transfer in Mixed-Valence{Fe^(Ⅲ)_(4)Fe^(Ⅱ)_(4)}Cubes
《CCS Chemistry》2022年第7期2452-2459,共8页Maolin You De-Xuan Gan Yi-Fei Deng Dong Shao Yin-Shan Meng Xiao-Yong Chang Yuan-Zhu Zhang 
supported by the Stable Support Plan Program of Shenzhen Natural Science Fund(no.20200925151834005);the National Natural Science Foundation of China(nos.21671095 and 21901108).
The engineering of switchable moleculeswith dramatic magnetic change is currently among themost active areas in chemical research.Here,two cyanide-bridged mixed-valence{Fe^(Ⅲ)_(4)Fe^(Ⅱ)_(4)}cubes were prepared,both ...
关键词：charge transfer Prussian blue analogs cyanide complexes MIXED-VALENCE molecular switches 
Synergistic effect of Ni^(Ⅱ)and Co/Fe^(Ⅲ)in doped mixed-valence phosphonate for enhancing electrocatalytic oxygen evolution被引量：1
《Green Energy & Environment》2022年第3期432-439,共8页Juan-Juan Hou Jian-Tao Yuan Wei Zhang Ying-Xia Wang Xian-Ming Zhang 
supported by the National Natural Science Foundation of China(NSFC 21871167);the National Natural Science Fund for Young Scholars of China(NSFC 21201114);the 1331 Engineering of Shanxi Province;Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2019L0464);Shanxi Province Science Foundation for Youths(201901D211391)。
Metal organophosphonates have been explored in energy-related fields due to their high chemical and thermal stability as a type of uniformly precursor,but only few of pristine metal organophosphonate are directly used...
关键词：PHOSPHONATE STABILITY organo 
Intelligently assembly of W_(18)O_(49)nanorod clusters with directionally generated oxygen vacancies and excellent electrochemical properties
《Nano Research》2022年第4期3575-3586,共12页Dan Zhou Xiaojiao Guo Yixiang Chen Xiaoyu Yuan Jinku Liu 
This work was supported by the National Natural Science Foundation of China(No.21878090);Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province(No.2020CL04).
Mixed-valence metallic compounds are a class of functional materials with peculiar electrochemical properties.Exploring the correlation between defects and corrosion resistance of mixed-valence metallic compounds is a...
关键词：oxygen vacancy directional generated W_(18)O_(49) mixed-valence metal oxide electrochemical properties 
Bandgap engineering of tetragonal phase CuFeS_(2)quantum dots via mixed-valence single-atomic Ag decoration for synergistic Cr(VI)reduction and RhB degradation被引量：1
《Chinese Chemical Letters》2021年第11期3450-3456,共7页Yangzi Shangguan Yuanhao Zhou Renji Zheng Xuezhen Feng Qiuyue Ge Ranhao Wang Dazhong Yang Wenfei Wei Xiaoyong Wu Jia Lin Hong Chen 
financially supported by the National Natural Science Foundation of China(Nos.21777045,61875119);Distinguished Young Scholar Fund from Natural Science Funds of Guangdong Province,China(No.2020B151502094);the program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,Shanghai Rising-Star Program(No.19QA1404000);Shanghai Talent Development Fund.
Bandgap engineering through single-atom site binding on semiconducting photocatalyst can boost the intrinsic activity,selectivity,carrier separation,and electron transport.Here,we report a mixed-valence Ag(0)and Ag(I)...
关键词：Single-atom catalysts Bandgap engineering Cr(VI)reduction Organic pollutants degradation Dyeing wastewater treatment 
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