MIXED-VALENCE

作品数:46被引量:19H指数:2
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相关期刊:《ChemPhysMater》《Chemical Research in Chinese Universities》《Journal of Energy Chemistry》《Science Bulletin》更多>>
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  • 期刊=Science China Chemistryx
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3D Co(II, III) mixed-valence metal-organic framework affording field-induced slow magnetic relaxation
《Science China Chemistry》2015年第6期1032-1038,共7页Sheng Zhang Xiangyu Liu Bin Liu Zhengqiang Xia Weitao Wang Qi Yang Hongshan Ke Qing Wei Gang Xie Sanping Chen Shengli Gao 
supported by the National Natural Science Foundation of China(21373162,21127004,21173168,21203149,21463020);the Natural Science Foundation of Shaanxi Province(11JS110,FF10091,SJ08B09)
A 3D mixed-valence Co(Ⅲ)-Co(Ⅱ) compound [Co9(bta)10(Hbta)2(H2O)10]n·[22(H2O)]n (1) (H2bta=N,N-bis(1H-tetrazole-5- yl)-amine) was hydrothermally synthesized by reaction of Co(NO3)2·6H2O with H2...
关键词:Co(Ⅱ  Ⅲ) mixed-valence metal-organic framework  slow magnetic relaxation 
From discrete [Mn_4] cluster to 1D complex: Two new mixed-valence manganese complexes with slow magnetization relaxation
《Science China Chemistry》2009年第9期1463-1469,共7页YANG PeiPei & LI LiCun Department of Chemistry, Nankai University, Tianjin 300071, China 
Supported by the National Natural Science Foundation of China (Grant Nos. 20471032 & 50672037) ;the Natural Science Foundation of Tianjin (Grant No. 09JCYBJC05600)
A tetranuclear manganese complex [Mn4(HL)4(MeOH)4(SCN)2]·3MeOH (1) and a one-dimensional assembly of [Mn4] units, [Mn4(HL)4(MeOH)4(N(CN)2)2]·2.5MeOH (2) (H3L = 2,6-bis(hydroxymethyl)-4-methyl-phenol), have been synt...
关键词:TETRANUCLEAR MANGANESE COMPLEX 1D COMPLEX MAGNETIC properties SLOW MAGNETIC relaxation 
Mixed-valence copper coordination polymers based on CuSCN or CuN_(3) as bridging motifs
《Science China Chemistry》2005年第z1期41-44,共4页FAN Guang,GAO Shengli,CHEN Sanping,ZENG Minghua & XIE Gang Department of Chemistry,Northwest University,Xi’an 710069,China Department of Chemistry,Guangxi Normal University,Guilin 541000,China 
supported by the National Natural Science Foundation of China(Grant No.2047104);the Education Committee of Shaanxi Province(Grants No.01JK229,FF02328 and 05JK291).
Two novel mixed valence copper coordination polymers, [Cu(2-pac)2(CuN3)(H2O)]n (1) and [Cu(2-pac)2(CuSCN)2]n (2), have been prepared through hydrothermal synthesis and analyzed for structure determination, which exhib...
关键词:HYDROTHERMAL synthesis  crystal structure  2-pyrazinecarboxylic acid  coordination polymer. 
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