supported by the National Natural Science Foundation of China(21373162,21127004,21173168,21203149,21463020);the Natural Science Foundation of Shaanxi Province(11JS110,FF10091,SJ08B09)
A 3D mixed-valence Co(Ⅲ)-Co(Ⅱ) compound [Co9(bta)10(Hbta)2(H2O)10]n·[22(H2O)]n (1) (H2bta=N,N-bis(1H-tetrazole-5- yl)-amine) was hydrothermally synthesized by reaction of Co(NO3)2·6H2O with H2...
Supported by the National Natural Science Foundation of China (Grant Nos. 20471032 & 50672037) ;the Natural Science Foundation of Tianjin (Grant No. 09JCYBJC05600)
A tetranuclear manganese complex [Mn4(HL)4(MeOH)4(SCN)2]·3MeOH (1) and a one-dimensional assembly of [Mn4] units, [Mn4(HL)4(MeOH)4(N(CN)2)2]·2.5MeOH (2) (H3L = 2,6-bis(hydroxymethyl)-4-methyl-phenol), have been synt...
supported by the National Natural Science Foundation of China(Grant No.2047104);the Education Committee of Shaanxi Province(Grants No.01JK229,FF02328 and 05JK291).
Two novel mixed valence copper coordination polymers, [Cu(2-pac)2(CuN3)(H2O)]n (1) and [Cu(2-pac)2(CuSCN)2]n (2), have been prepared through hydrothermal synthesis and analyzed for structure determination, which exhib...