support from the National Natural Science Fund for Distinguished Young Scholars of China(No.22025107);Shaanxi Fundamental Science Research Project for Chemistry&Biology(No.22JHZ003);the National Youth Top-notch Talent Support Program of China,Xi’an Key Laboratory of Functional Supramolecular Structure and Materials,and the FM&EM International Joint Laboratory of Northwest University。
Conventionally,organic radicals adhere to the Aufbau principle,the energy level of the singly occupied molecular orbital(SOMO)is not below the highest occupied molecular orbital(HOMO),but somewhat abnormal phenomena h...
the National Key Research and Development Program of China(No.2019YFC1908400);the National Natural Science Foundation of China(Nos.52174334,52374413);the Jiangxi Provincial Cultivation Program for Academic and Technical Leaders of Major Subjects,China(Nos.20212BCJ23007,20212BCJL23052);the Jiangxi Provincial Natural Science Foundation,China(Nos.20224ACB214009,20224BAB214040);the Double Thousand Plan of Jiangxi Province,China(No.S2021GDQN2970);the Distinguished Professor Program of Jinggang Scholars in Institutions of Higher Learning of Jiangxi Province,China.
The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasib...
supported by the National Natural Science Foundation of China(Grant Nos.12122405,52072188,and 12274169);the National Key R&D Program of China(Grant No.2022YFA1402304);the Program for Changjiang Scholars and Innovative Research Team in University(Grant No.IRT_15R23);the Jilin Provincial Science and Technology Development Project(Grant No.20210509038RQ)。
Superconductivity in compressed sulfur hydride(H_(3)S)at above 200 K has attracted great interest in the study of hydrogen-based superconductors.However,the pressure required to stabilize H_(3)S is 150 GPa,posing sign...
123I is the most widely used cyclotron-produced radio-halogen in medical research. In this paper, excitation function formulae for the nuclear reactions of 123I production are introduced. 124Te (p, 2n)123I and 127I (p...
supported by the Chinese National Science Fund for Distinguished Young Scholars to Dr.Gao Jian-Feng(42025301).
The Dexing porphyry deposit is the largest porphyry Cu–Mo–Au deposit in South China.Biotite composition can record the physicochemical conditions and evolution history of magmatic-hydrothermal system.Biotite from th...
supported by the Fundamental Research Funds for the Central Universities(FRF-TP-18-080A1);the National Natural Science Foundation of China(Grant Nos.42002076,41930427,41725009,U1603244);the Science and Technology Planning of Guangdong Province,China(2020B1212060055)。
To constrain the ore-fluid source(s)of the Laoshankou Fe-Cu-Au deposit(Junggar orogen,NW China),we analyzed the fluid inclusion(FI)noble gas(Ar,Kr and Xe)and halogen(Cl,Br and I)compositions in the hydrothermal epidot...
the National Natural Science Foundation of China(Grant Nos.51701180,51871201,U1802254)。
The three halogen solids(Cl_(2),Br_(2),and I_(2))have the isostructural diatomic molecular phaseⅠwith a space group of Cmca at ambient pressure.At high pressure,they all go through an intermediate phaseⅤwith incomme...
the National Natural Science Foundation of China(No.21701089).
Main observation and conclusion The assembly of[Et4N][Tp*WS3](1)with CuX(Tp*=hydridotris(3,5-dimethylpyrazol-1-yl)borate;X=Cl,Br,andI)or[Cu(MeCN)][PF6]in the presence of tetratopic ligand hexamethylenetetramine(HMT)af...
supported by NSFCs (41306199);the Dean Research Funds for CAS Hefei Institute (YZJJ201304)
The reactive halogens play key roles in the destruction of boundary layer ozone by catalytic reactions and provide a fast pathway to the sedimentation of elemental gaseous mercury.The presence of bromine oxides in the...
Project (51201079) supported by the National Natural Science Foundation of China;Project (2012Z099) supported by the Scientific Research Fund of Department of Education of Yunnan Province,China;Project (KKSY201251033) supported by the Scientific Research Foundation for Introduced Talents of KMUST,China
The adsorption of low-coverage of F and Cl adatoms on the Mg(0001) surface was investigated using first-principles calculations based on the density functional theory(DFT).The stability of the(2×2) structures f...