the National Natural Science Foundation of China(Nos.21772138 and 21672157);the project of scientific and technologic infrastructure of Suzhou(No.SZS201708);PAPD。
Novel and efficient Mn(OAc)_(3)·2 H_(2)O promoted radical addition-[4+1]cyclization relay of 3-indolymethanols and phosphites was disclosed,which afforded 1,2-oxaphospholoindole derivatives in moderate to good yields...
financial support from the National Natural Science Foundation of China(Nos.21172213,21302109,21402184,and 21572217)
A simple and highly efficient one-pot method for the construction of α-hydroxyketone phosphates from terminal alkynes and H-phosphine oxides has been developed in the presence of PhI(OAc)2 and H20. The present prot...
support from the National Natural Science Foundation of China(Nos.20962018, 20862015 and 20562011)
A series of novel Schiff bases bearing triazole structure were synthesized and characterized by LR and NMR. Mn(OAc)2/Schiff base efficiently catalyzed Henry reaction of nitroalkanes with aldehydes to produce the cor...
An attempt has been made to prepare terephthalic acid(TPA) by solvent-free oxidation of p-xylene(PX) with air over tetra(pchlorophenylporphinato) manganese chloride(T(p-Cl)PPMnCl) and cobalt acetate.The co-c...
A simple Cu(OAc)2 catalyzed Sonogashira coupling protocol is presented. It was found that the couplings of a variety of aryl halides with terminal alkynes were conducted smoothly to afford the corresponding desired ...
The authors are grateful to the National Natural Science Foundations of China(No.20372012);the Natural Science Foundations of Liaoning(No.20032099)for the generous financial support.
The photopromoted methoxycarbonylation of olefin with methyl formate catalyzed by Co(OAc)2 at ambient conditions has been carried out. The results indicated that the reaction activity increased with the increasing t...
A mild and efficient oxidation of alcohols to the corresponding carbonyl compounds using the PhI(OAc)2 (1.1 eq.) with n-Bu4NBr (8 mol %) in water at room temperature is described. This new procedure is very simple and...
l-Acetoxy allylic phosphonates rearrange regioselectively to γ-acetoxy α,β-unsaturated phosphonates under the catalysis of Pd(0). l-Acetoxy allylic phosphonates act as the precursors of phosphonatedπ-allylic cati...