supported by the National Natural Science Foundation of China(51833001,51921002,52103001);the China Postdoctoral Science Foundation(2021T140007,2020M680191).
Polymers with tunable helicity and naked-eye structural change under external stimuli are valuable for fabricating smart materials. Herein, we report a novel thermoresponsive color and fluorescent polyphenylacetylene ...
In this paper, the stereoselective homogeneous catalysis polymerization of phenylacetylene by using two kinds of catalysts W(CO)_5CH_3I and W(CO)_4I_2 produced from UV laser photolysis of W (CO)_6 in CH_3I, I_2—C_6H_...
A new kind of catalyst WOBr_4,which can be used in the polymerization of phenylacetylene(PhA),has been synthesized.The obtained polyphenylcetylene(PPhA) using WOBr_4 as catalyst is soluble、fusible、with brown-red col...
The CO_2 quenching method has been used for the first time to determine the active complex concen- tration in Nd(naph)_3-Al(i-Bu)_3 catalyst system for polymerization of phenylacetylene into polyphenylacetylene(PPA)fi...