National Basic Research Program of China(973 Program)(No.2011CB606103);National High-Tech Research and Development Program of China(863 Program)(No.2012AA03212);the Fundamental Research Funds for the Central Universities,China(No.11D10625)
The relationship between property and structure of poly( p-phenylene terephthalamide)( PPTA) was investigated for the purpose of obtaining products with better performance. PPTA fiber subjected to heat treatment under...
Poly(p-phenylene terephthalamide)(PPTA)pulp was prepared by polycondensation of the p-phenylene diamine(PPDA)with terephthaloyl chloride(TPC)in the completely anhydrous solvent system of N-methyl pyrrolidone(NMP)havin...
Poly ( m-phenylene isophthalamine) (PMIA) and Poly( p-phenylene terphthalamine) (PPTA) are among the most important high-temperature resistant aramid fibers. The pyrolysis behaviors of these two fibers under i...
High viscous PPTA copolymer is prepared by low temperature solution copolycondensation of terephth-aloylchloride, p-phenylenediamine and p, p'-diamino-phenylpiperazine in the NMP-CaCl2 solvent system. The inherent vis...
The morphology of PPTA pulp is investigated by means of optical microscope and scanningelectron microscope (SEM). It shows that PPTA pulp has feather-like branch, needle point-likeend, and irregular cross-section, whi...
Super pure 2,5-dichloroterephthaloyl dichloride (DDC) was prepared by chlorination andcontrolled by Gas Chromatography(GC) method. As a third monomer, DDC waspolycondensated into chlorinated PPTA together with terepht...
PPTA fibres have high axial tensile strength,but the transverse links at the macromolecularlevel of the fibres are low.The high orientation and crystallization of the PPTA fibres leads to alow resistance to bending fa...