SALTS

作品数：329被引量：429H指数：8
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相关作者：刘红霞李润涛余爱农胡卫兵向必坤更多>>
相关机构：北京大学合肥通用机械研究院浙江中广电器有限公司湖北民族大学更多>>
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Multi-component hydrogen-bonding salts formed between imidazole and aromatic acids:Synthons cooperation and crystal structures被引量：2
《Science China Chemistry》2012年第10期2115-2122,共8页WANG Lei ZHAO Lei LIU Meng CHEN RuiXin YANG Yu GU YuanXiang 
supported by the National Natural Science Foundation of China (20701023, 20971076);the Natural Science Foundation of Shandong Province, China (BS2010NJ004,2009ZRB019KH)
Imidazole base was crystallized with different aromatic carboxylic acids 2,4-dihydroxybenzoic acid, 5-chlorosalicylic acid, and 1,8-naphthalic acid, affording three new binary molecular organic salts of [(C 3 H 5 N 2 ...
关键词：crystal engineering supramolecular synthons IMIDAZOLE organic salts 
Mechanism of palladium-catalyzed decarboxylative cross-coupling between cyanoacetate salts and aryl halides被引量：5
《Science China Chemistry》2012年第10期2057-2062,共6页JIANG YuanYe FU Yao LIU Lei 
supported by the National Natural Science Foundation of China (20972148);CAS;NECT (08-0519)
Recently we reported Pd-catalyzed decarboxylative cross-coupling of cyanoacetate salts with aryl halides and triflates. This reaction shows good functional group tolerance and is useful for the synthesis of-aryl nitri...
关键词：PALLADIUM catalytic DECARBOXYLATION MECHANISM density functional theory 
Distinct phase transitions and dielectric anomalies in two 4-methylanilinium salts被引量：2
《Science China Chemistry》2012年第2期201-207,共7页ZHANG Wen XU RuiJun 
supported by the National Natural Science Foundation of China (21071030);Natural Science Foundation of Jiangsu Province(BK2010425)
Solid-state phase transitions of 4-methylanilinium perchlorate （4-CH3C6H4NH3.C104, 1） and tetrafluoroborate （4-CH3C6H4- NH3-BF4, 2） were investigated with variable-temperature X-ray single-crystal structure analys...
关键词：organic-inorganic hybrid compounds DIELECTRICITY phase transition crystal structure switchable molecular dielectrics 
Thermochemical properties and thermokinetic behavior of energetic triazole ionic salts被引量：4
《Science China Chemistry》2011年第3期461-474,共14页ZHAO FengQi XUE Liang XING XiaoLing HU RongZu ZHOU ZhiMing GAO HongXu YI JianHua XU SiYu PEI Qing 
supported by the National Natural Science Foundation of China (20573098);the Science and Technology Foundation of National Key Lab of Science and Technology on Combustion and Explosion in China (9140C3503030805)
The properties of dissolution in different solvents,the specific heat capacity and thermal decomposition process under the non-isothermal conditions for energetic triazole ionic salts 1,2,4-triazolium nitrate(1a),1,2,...
关键词：energetic triazole ionic salts thermochemical properties thermokinetic behavior thermal safety 
Recent studies on chemistry of novel μ-CO-containing butterfly Fe/E (E=S,Se,Te) cluster salts被引量：1
《Science China Chemistry》2009年第1期1-14,共14页SONG LiCheng Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China 
Supported by the National Natural Science Foundation of China (Grant Nos. 20372034 & 20772059);the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20070055005)
This article describes recent developments in chemical study on a series of butterfly-shaped μ-CO-containing Fe/E (E = S, Se, Te) cluster salts. These salts include eleven novel cluster anions, which are the single b...
关键词：BUTTERFLY CLUSTER synthesis structure reaction mechanism 
A novel method for the formylation of Grignard reagent
《Science China Chemistry》2005年第z1期25-28,共4页SHI Zhen WANG Luyao GU Huan LI Jianli BAI Yinjuan YANG Bingqin 
supported by the National Natural Science Foundation of China(Grant No.20172041);the Provincial Natural Science Foundation of Shaanxi Province(Grant No.2003B12).
A facile and efficient method for the formylation of Grignard reagent was reported, and a new approach for the preparation of aldehydes from Grignard reagent and benzimidazolium salts was provided.
关键词：benzimidazolium salts  GRIGNARD reagent  formylation  aldehyde  synthesis. 
STUDIES ON REDOX PROPERTIES OF HETEROPOLY ACIDS (SALTS) AND THEIR DERIVATIVES WITH KEGGIN AND DAWSON STRUCTURES
《Science China Chemistry》1990年第9期1032-1039,共8页王恩波 陆新红 赵世良 刘景福 张保建 
Project supported by the National Natural Science Foundation of China.
We have systematically studied redox properties of two series of several dozen heteropoly acids (salts) and their derivatives with vanadium and rare-earth elements with Keggin and Dawson structures, e. g. LnHSiMo_(12)...
关键词：HETEROPOLY COMPOUNDS KEGGIN strueture DAWSON structure oxidation reduction 
MOLECULAR VOLUMES OF SALTS. WITH TRIANGULAR RADICALS
《Science China Chemistry》1990年第4期485-494,共10页张金民 叶大年 
Project supported by the National Natural Science Foundation of China.
The present paper discusses some characteristics of the molecular volumes of carbonates, nitrates and borates. It confirms that the molecular volume of H_2O in the hydrates of this kind of salts approximates to a cons...
关键词：CARBONATE nitrate BORATE molecular volume additivity. 
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