supported by the National Natural Science Foundation of China(21971173,22001185,22171201);the Natural Science Foundation of Jiangsu Province(BK20200852);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
A conceptually novel,trifunctional sulfoximine-mediatedγ-functionalization of unactivated C(sp^(3))–H bonds has been achieved.The reaction is initiated by the photo-induced homolytic cleavage of an N–S bond in the ...