supported by the National Natural Science Foundation of China(22025203 and 22121005);the National Key R&D Program of China(2021YFA1501102);Haihe Laboratory of Sustainable Chemical Transformations,Tianjin.D.M.acknowledges support from the Tencent Foundation through the XPLORER PRIZE.
The direct epoxidation of propylene with molecular oxygen represents a desired route for propylene oxide(PO)production with 100%theoretical atomic economy.However,this aerobic epoxidation reaction suffers from the app...