TITANOSILICATE

作品数:13被引量:18H指数:2
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Direct propylene epoxidation with molecular oxygen over titanosilicate zeolites
《National Science Review》2024年第11期133-141,共9页Weijie Li Bin Qin Zhuoya Dong Yuchao Chai Guangjun Wu Yanhang Ma Meng Wang Xingwu Liu Ding Ma Landong Li 
supported by the National Natural Science Foundation of China(22025203 and 22121005);the National Key R&D Program of China(2021YFA1501102);Haihe Laboratory of Sustainable Chemical Transformations,Tianjin.D.M.acknowledges support from the Tencent Foundation through the XPLORER PRIZE.
The direct epoxidation of propylene with molecular oxygen represents a desired route for propylene oxide(PO)production with 100%theoretical atomic economy.However,this aerobic epoxidation reaction suffers from the app...
关键词:titanosilicate zeolites propylene epoxidation molecular oxygen 
Structured binder‐free MWW‐type titanosilicate with Si‐rich shell for selective and durable propylene epoxidation被引量:8
《Chinese Journal of Catalysis》2021年第9期1561-1575,共15页Jinpeng Yin Xin Jin Hao Xu Yejun Guan Rusi Peng Li Chen Jingang Jiang Peng Wu 
国家自然科学基金(21533002,21872052,21972044);国家重点研发计划(2016YFA0202804);中央高校基本科研业务费专项资金。
Selective and durable fixed‐bed catalysts are highly desirable for developing eco‐efficient HPPO(hydrogen peroxide propylene oxide)process.The powder titanosilicate catalysts must be shaped before being applied in i...
关键词:Propylene epoxidation TITANOSILICATE Binder‐free formed catalyst RECRYSTALLIZATION MICROENVIRONMENT 
Fabrication of titanosilicate pillared MFI zeolites with tailored catalytic activity被引量:1
《Frontiers of Chemical Science and Engineering》2020年第5期772-782,共11页Baoyu Liu Qiaowen Mu Jiajin Huang Wei Tan Jing Xiao 
This work was funded by the National Natural Science Foundation of China(Grant Nos.21808040,51476176,and 21776049);The support of the Science and Technology Program of Guangzhou,China(Grant No.201804010172)is also gratefully acknowledged.
Titanosilicate pillared MFI zeolite nanosheets were successfully synthesized by infiltrating the mixed tetraethyl orthosilicate(TEOS)/tetrabutyl orthotitanate(TBOT)solvent into the gallery space between adjacent MFI z...
关键词:MFI zeolite catalysis NANOSHEETS FABRICATION 
Crossed intergrowth triggered TS-2 microsphere:Formation mechanism,modification and catalytic performance被引量:2
《Chinese Journal of Catalysis》2020年第7期1109-1117,共9页Hao Xu Wenwen Tian Liping Xu Xin Jin Teng Xue Li Chen Mingyuan He Peng Wu 
国家自然科学基金(21533002,21603075,21872052);科技部重大项目(2016YFA0202804).
TS-2 microspheres,consisting of intergrown primary nanocrystals,was prepared by controlling the synthetic parameters.The effects of the amount of quaternary ammonium cations as structure-directing agent,H2O/Si ratio,t...
关键词:TITANOSILICATE TS-2 microsphere Crossed intergrowth Ammoximation reaction POST-TREATMENT 
Systematic Study of Ti-Distribution in Titanosilicate *BEA Zeolites via Symmetry-Adapted Enumeration
《Chinese Journal of Chemistry》2019年第6期593-596,共4页Lin Li Jiaze Wang Yi Li Jihong Yu 
the National Key Research and Development Program of China (No.2016YFB0701100);the National Natural Science Foundation of China (Nos.21622102 and 21621001);the National 111 Project (B17020);Program for JLUSTIRT;High Performance Computing Center of Jilin in University.
The high performance of titanosilicate zeolites in various industrial oxidation reactions is highly affected by the distribution of Ti atoms in their frameworks. Because of their structural complexity, previous theore...
关键词:zeolites BEA topology Ti-distribution thermodynamics BOLTZMANN statistics high-throughput calculation 
Recent Progresses in Titanosilicates被引量:3
《Chinese Journal of Chemistry》2017年第6期836-844,共9页Hao Xu Peng Wu 
Titanosilicates, with tetrahedrally coordinated Ti4+ ions in highly crystalline zeolite frameworks, are a class of unique heterogeneous catalysts useful for the liquid-phase selective oxidation reactions. The great s...
关键词:TITANOSILICATE selective oxidation reactions novel topology new morphology chemical modification 
Synthesis of single crystal-like hierarchically mesoporous titanosilicate Ti-SBA-1被引量:2
《Chinese Chemical Letters》2015年第10期1269-1272,共4页Na Li Rui Chen Jing Miao Peng Zhou Hai-Bin Yu Tie-Hong Chen 
supported by National Science Foundation of China (Nos. 21373116 and 21421001);Tianjin Natural Science Research Fund (No. 13JCYBJC18300);RFDP (No. 20120031110005);the Technology Planning Project of Hunan Province (No. 2014SK2019);National Science Foundation for Post-doctoral Scientists of China (No. 2014T70774);the Scientific Research Fund of Hunan Provincial Education Department (No. 14C0343)
Hierarchically mesoporous titanosilicate Ti-SBA-1 was synthesized with organic mesomorphous complexes of polyelectrolyte(poly(acrylic acid)(PAA)) and cationic surfactant(hexadecyl pyridinium chloride(CPC)) a...
关键词:Ti-SBA-1 Hierarchical Mesoporous Titanosilicate 
Post-synthesis and catalytic performance of FER type sub-zeolite Ti-ECNU-8
《Chinese Chemical Letters》2014年第12期1511-1514,共4页Bo-Ting Yang Peng Wu 
the National Natural Science Foundation of China(Nos.21373089,U1162102);PhD Programs Foundation of Ministry of Education(No.2012007613000);the National Key Technology R&D Program(No.2012BAE05B02);the Shanghai Leading Academic Discipline Project(No.B409)
A titanosilicate Ti-ECNU-8 with a FER type sub-zeolite structure was developed by pots-synthesis and applied to the epoxdiation of alkenes with hydrogen peroxide.A controlled acid treatment on the pure silica layered ...
关键词:Sub-zeolite ECNU-8 Titanosilicate Epoxidation Layered zeolite 
Controllable synthesis and photocatalytic activities of rod-shaped mesoporous titanosilicate composites with varied aspect ratios被引量:1
《Chinese Chemical Letters》2014年第6期962-966,共5页Feng-Jiao Chen Chang-Wang Shao Min-Nan Zhao Zhao-Sheng Bu Yan Zhang Xiao-Nan Dai Guo-Wei Zhou 
supported by the National Natural Science Foundation of China(Nos.20976100,51372124);the Natural Science Foundation of Shandong Province(Nos.ZR2010BM013, ZR2011BQ009);the Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province(No. 201207);Key Laboratory of Colloid and Surface Chemistry, Ministry of Education(Shandong University,No.201205)
Rod-shaped mesoporous titanosilicate composites (RMTSs) with controllable aspect ratios (ARs) were fabricated using cetyltrimethylammonium bromide (CTAB) and ammonium hydroxide (NH4OH) at a continuous stirring...
关键词:TITANOSILICATE Aspect ratio Growth direction Photocatalytic activity 
Impact of photogenerated charge behaviors on luminescence of Eu^(3+) -incorporated microporous titanosilicate ETS-10被引量:1
《Science China Chemistry》2013年第4期428-434,共7页GUO XingXing WEI Xiao WANG KaiXue WANG JingFeng CHEN JieSheng 
supported by the National Natural Science Foundation of China (21201121, 21271128);the National Basic Research Program of China (2011CB808703)
A series of Eu3+ -incorporated ETS-10 samples were successfully prepared based on the traditional ion exchange method. The relationship between photogenerated charge behaviors and luminescent properties has been inves...
关键词:ETS-IO ion exchange photoluminescence photogenerated charges PHOTOVOLTAGE SENSITIZATION 
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