supported by the National Natural Science Foundation of China(22025203 and 22121005);the National Key R&D Program of China(2021YFA1501102);Haihe Laboratory of Sustainable Chemical Transformations,Tianjin.D.M.acknowledges support from the Tencent Foundation through the XPLORER PRIZE.
The direct epoxidation of propylene with molecular oxygen represents a desired route for propylene oxide(PO)production with 100%theoretical atomic economy.However,this aerobic epoxidation reaction suffers from the app...
Selective and durable fixed‐bed catalysts are highly desirable for developing eco‐efficient HPPO(hydrogen peroxide propylene oxide)process.The powder titanosilicate catalysts must be shaped before being applied in i...
This work was funded by the National Natural Science Foundation of China(Grant Nos.21808040,51476176,and 21776049);The support of the Science and Technology Program of Guangzhou,China(Grant No.201804010172)is also gratefully acknowledged.
Titanosilicate pillared MFI zeolite nanosheets were successfully synthesized by infiltrating the mixed tetraethyl orthosilicate(TEOS)/tetrabutyl orthotitanate(TBOT)solvent into the gallery space between adjacent MFI z...
TS-2 microspheres,consisting of intergrown primary nanocrystals,was prepared by controlling the synthetic parameters.The effects of the amount of quaternary ammonium cations as structure-directing agent,H2O/Si ratio,t...
the National Key Research and Development Program of China (No.2016YFB0701100);the National Natural Science Foundation of China (Nos.21622102 and 21621001);the National 111 Project (B17020);Program for JLUSTIRT;High Performance Computing Center of Jilin in University.
The high performance of titanosilicate zeolites in various industrial oxidation reactions is highly affected by the distribution of Ti atoms in their frameworks. Because of their structural complexity, previous theore...
Titanosilicates, with tetrahedrally coordinated Ti4+ ions in highly crystalline zeolite frameworks, are a class of unique heterogeneous catalysts useful for the liquid-phase selective oxidation reactions. The great s...
supported by National Science Foundation of China (Nos. 21373116 and 21421001);Tianjin Natural Science Research Fund (No. 13JCYBJC18300);RFDP (No. 20120031110005);the Technology Planning Project of Hunan Province (No. 2014SK2019);National Science Foundation for Post-doctoral Scientists of China (No. 2014T70774);the Scientific Research Fund of Hunan Provincial Education Department (No. 14C0343)
Hierarchically mesoporous titanosilicate Ti-SBA-1 was synthesized with organic mesomorphous complexes of polyelectrolyte(poly(acrylic acid)(PAA)) and cationic surfactant(hexadecyl pyridinium chloride(CPC)) a...
the National Natural Science Foundation of China(Nos.21373089,U1162102);PhD Programs Foundation of Ministry of Education(No.2012007613000);the National Key Technology R&D Program(No.2012BAE05B02);the Shanghai Leading Academic Discipline Project(No.B409)
A titanosilicate Ti-ECNU-8 with a FER type sub-zeolite structure was developed by pots-synthesis and applied to the epoxdiation of alkenes with hydrogen peroxide.A controlled acid treatment on the pure silica layered ...
supported by the National Natural Science Foundation of China(Nos.20976100,51372124);the Natural Science Foundation of Shandong Province(Nos.ZR2010BM013, ZR2011BQ009);the Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province(No. 201207);Key Laboratory of Colloid and Surface Chemistry, Ministry of Education(Shandong University,No.201205)
Rod-shaped mesoporous titanosilicate composites (RMTSs) with controllable aspect ratios (ARs) were fabricated using cetyltrimethylammonium bromide (CTAB) and ammonium hydroxide (NH4OH) at a continuous stirring...
supported by the National Natural Science Foundation of China (21201121, 21271128);the National Basic Research Program of China (2011CB808703)
A series of Eu3+ -incorporated ETS-10 samples were successfully prepared based on the traditional ion exchange method. The relationship between photogenerated charge behaviors and luminescent properties has been inves...