AZO

作品数:484被引量:791H指数:11
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相关机构:中国科学院深圳大学哈尔滨工业大学浙江大学更多>>
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A round-trip journey of electrons:Electron catalyzed direct fixation of N_(2)to azos
《Chinese Journal of Catalysis》2025年第1期386-393,共8页Baijing Wu Jinrui Li Xiaoxue Luo Jingtian Ni Yiting Lu Minhua Shao Cunpu Li Zidong Wei 
国家重点研发计划(2022YFC2105904);国家自然科学基金(22478043,2209003052021004,U21A20312,22075033)。
The triple bond in N_(2)has an extremely high bond energy and is thus difficult to break.N_(2)is commonly converted into NH3 artificially via the Haber-Bosch process,and NH_(3)can be utilized to produce other nitrogen...
关键词:Fixed N_(2) AZO Electron catalyzed strategy "Brick trowel"transition state Arylradicals 
Visible light-responsive azo-based smart materials: Design, performance, and applications in energy storage
《Smart Molecules》2024年第4期146-166,共21页Shurui Lv Yuang Zhang Wentao Wang Shufen Zhang Bingtao Tang 
National Natural Science Foundation of China(22108026,22178050);the Young Elite Scientists Sponsorship Program by CAST(2021QNRC001);the Natural Science Foundation of Liaoning Province(2022-BS-091);the Dalian Science and Technology Innovation Fund Young Tech Star(2022RQ008);the Fundamental Research Funds for the Central Universities(DUT22LAB610).
Azobenzene and its derivatives are the most extensively investigated and applied molecular photoswitches,which can undergo reversible transformation between trans and cis isomers upon irradiation with light at specifi...
关键词:energy storage materials PHOTOCHEMISTRY 
Interfacial charge effects of supported-metal-cluster heterostructures on azo hydrogenation catalyzation
《Nano Research》2024年第5期3853-3862,共10页Zhenhua Gu Jingli Zhang Zijun Zhang Qingxue Mu Liangchong Yu Taolei Sun Lei Shen Guanbin Gao 
supported by the National Natural Science Foundation of China(Nos.52273110,21975191,52372271,22173070);the Knowledge Innovation Program of Wuhan Shuguang Project,and the Fundamental Research Funds for the Central Universities(WUT:2023Ⅲ013GX).
The impact of interfacial charge on catalytic performance of supported-metal-cluster(SMC)heterostructures remains unclear,hindering efforts to develop high-performance SMC catalysts.Herein we systematically investigat...
关键词:interfacial charge effect supported-metal-cluster catalyst azo hydrogenation graphene supported gold nanoclusters 
Catalytic asymmetric dearomative azo-Diels–Alder reaction of 2-vinlyindoles
《Chinese Chemical Letters》2024年第4期357-362,共6页Yu-Hang Miao Zheng-Xu Zhang Xu-Yi Huang Yuan-Zhao Hua Shi-Kun Jia Xiao Xiao Min-Can Wang Li-Ping Xu Guang-Jian Mei 
the generous financial support from Natural Science Foundation of Henan Province (No.222300420084);application research plan of Key Scientific Research Projects in Colleges and Universities of Henan Province (No.22A150056);the Youth Innovation Team Program in Colleges and Universities of Shandong Province (No.2022KJ228);National Natural Science Foundation of China (No.22208302)。
Due to the high electrophilic nature of azo-dienophiles, azo-Diels–Alder proceeds rapidly even without the need of a catalyst and is therefore regarded as the “click reaction”. This spontaneity causes strong backgr...
关键词:Catalytic asymmetric dearomatization Azo-Diels–Alder reaction 2-Vinylindoles Chiral phosphoric acid Tetracyclic indole derivatives 
Linker-activated covalent organic frameworks with azo bridges
《Chinese Chemical Letters》2023年第8期3-5,共3页Wei-Lei Zhou Yong Chen 
As an important functional group,azo derivatives(-N=N-)have attracted wide attention due to their excellent properties,for their narrow bandgap,Lewis base property,photo-isomerization and redox activity,in chemistry a...
关键词:properties NARROW BENZENE 
Synthesis,Structure,and Optical-response Magnetic Property of a Heteroarene-azo Functionalized Mn_(19) Cluster被引量:1
《Chinese Journal of Chemistry》2023年第14期1667-1672,共6页Yongkai Deng Yingying Wu Zhaoyang Li Zvonko Jagličić Rakesh Kumar Gupta Chenho Tung Di Sun 
financially supported by the National Natural Science Foundation of China(Grant Nos.52261135637,22171164);the Natural Science Foundation of Shandong Province(No.ZR2022QB191);the Taishan Scholar Project of Shandong Province of China(Nos.tsqn201812003 and ts20190908);the Instrument Improvement Funds of Shandong University Public Technology Platform(No.ts20220102);the Slovenian Research Agency(Grant No.P2-0348).
Metal clusters with photoswitching ligands can undergo magnetic changes under light radiation,which makes them potential optical-response magnetic-switching materials.Herein,a photoswitchable Mn-oxo cluster[Mn^(II)_(1...
关键词:CRYSTALSTRUCTURE Cluster compounds PHOTOCHROMISM Magnetic properties Stimuli-responsive molecular magnet 
A cobalt redox switch driving alcohol dehydrogenation by redox coupled molecular swing
《Chinese Chemical Letters》2023年第6期459-462,共4页Guoling Li Yang Liu Wei Wang Zhu Zhuo Yougui Huang 
supported by the National Natural Science Foundation of China(Nos.21871262,21805275 and 21901242);the Natural Science Foundation of Fujian Province(No.2019J01130);the Recruitment Program of Global Youth Experts。
Developing redox switches that not only perform specific mechanical movements but also drive important chemical reactions is important but a great challenge.Herein,we report a redox pair of cobalt species(Co^(Ⅲ)/Co^(...
关键词:Redox switch Alcohol dehydrogenation Azo-ligand hydrogenation Cobalt complex Mechanical motion 
Azo group-enabled metal-and oxidant-free alkenyl C-H thiolation:Access to stereodefined tetrasubstituted acyclic olefins
《Green Synthesis and Catalysis》2023年第1期67-70,共4页Hao-Jie Gao Yu-Hang Miao Shi-Kun Jia Na Li Li-Ping Xu Wei Wang Min-Can Wang Guang-Jian Mei 
Financial support from the Natural Science Foundation of Henan Province(No.222300420084);application research plan for key scientific research projects in colleges and universities of Henan Province(No.22A150056);Zhengzhou University(JC22261005),and the National Natural Science Foundation of China(No.21871237)are gratefully acknowledged.
Metal-and oxidant-free alkenyl C–H thiolation enabled by the azo group had been established for the modular synthesis of tetrasubstituted acyclic olefins.The reaction was performed under mild reaction conditions with...
关键词:Tetrasubstituted acyclic olefins Azo group C-H thiolation METAL-FREE 
Catalyst-free nitro-coupling synthesis of azo-linked conjugated microporous polymers with superior aqueous energy storage capability被引量:2
《Science China Materials》2022年第4期958-966,共9页Dianlei Fang Xinlei Wang Shijie Zhang Lingyan Sheng Jian Tang Jie Zhou Weihua Tang 
supported by the National Natural Science Foundation of China(51861145401,21905136);the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions。
Developing methods to construct conjugated microporous polymers(CMPs)with desirable structures is a crucial undertaking.However,obtaining azo-CMPs with extended azaacene cores is immensely challenging.Herein,we disclo...
关键词:conjugated microporous polymers nitro-coupling AZO hydrothermal reaction energy storage 
Stepwise Fabrication of Proton-conducting Covalent Organic Frameworks for Hydrogen Fuel Cell Applications
《Chemical Research in Chinese Universities》2022年第2期461-467,共7页JIA Shuping ZHAO Peng LIU Qi CHEN Yao CHENG Peng YANG Yi ZHANG Zhenjie 
supported by the National Natural Science Foundation of China(No.21971126);the 111 Projects of China(No.B12015);the Frontiers Science Center for New Organic Matter,China(No.63181206).
Exploring new materials to manufacture proton-conducting membranes(PEMs)for fuel cells is highly significant.In this work,we fabricated two robust and highly crystalline porous covalent organic frameworks(COFs)via a s...
关键词:Covalent organic framework Azo and amino group MEMBRANE Proton conduction Fuel cell 
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