The triple bond in N_(2)has an extremely high bond energy and is thus difficult to break.N_(2)is commonly converted into NH3 artificially via the Haber-Bosch process,and NH_(3)can be utilized to produce other nitrogen...
National Natural Science Foundation of China(22108026,22178050);the Young Elite Scientists Sponsorship Program by CAST(2021QNRC001);the Natural Science Foundation of Liaoning Province(2022-BS-091);the Dalian Science and Technology Innovation Fund Young Tech Star(2022RQ008);the Fundamental Research Funds for the Central Universities(DUT22LAB610).
Azobenzene and its derivatives are the most extensively investigated and applied molecular photoswitches,which can undergo reversible transformation between trans and cis isomers upon irradiation with light at specifi...
supported by the National Natural Science Foundation of China(Nos.52273110,21975191,52372271,22173070);the Knowledge Innovation Program of Wuhan Shuguang Project,and the Fundamental Research Funds for the Central Universities(WUT:2023Ⅲ013GX).
The impact of interfacial charge on catalytic performance of supported-metal-cluster(SMC)heterostructures remains unclear,hindering efforts to develop high-performance SMC catalysts.Herein we systematically investigat...
the generous financial support from Natural Science Foundation of Henan Province (No.222300420084);application research plan of Key Scientific Research Projects in Colleges and Universities of Henan Province (No.22A150056);the Youth Innovation Team Program in Colleges and Universities of Shandong Province (No.2022KJ228);National Natural Science Foundation of China (No.22208302)。
Due to the high electrophilic nature of azo-dienophiles, azo-Diels–Alder proceeds rapidly even without the need of a catalyst and is therefore regarded as the “click reaction”. This spontaneity causes strong backgr...
As an important functional group,azo derivatives(-N=N-)have attracted wide attention due to their excellent properties,for their narrow bandgap,Lewis base property,photo-isomerization and redox activity,in chemistry a...
financially supported by the National Natural Science Foundation of China(Grant Nos.52261135637,22171164);the Natural Science Foundation of Shandong Province(No.ZR2022QB191);the Taishan Scholar Project of Shandong Province of China(Nos.tsqn201812003 and ts20190908);the Instrument Improvement Funds of Shandong University Public Technology Platform(No.ts20220102);the Slovenian Research Agency(Grant No.P2-0348).
Metal clusters with photoswitching ligands can undergo magnetic changes under light radiation,which makes them potential optical-response magnetic-switching materials.Herein,a photoswitchable Mn-oxo cluster[Mn^(II)_(1...
supported by the National Natural Science Foundation of China(Nos.21871262,21805275 and 21901242);the Natural Science Foundation of Fujian Province(No.2019J01130);the Recruitment Program of Global Youth Experts。
Developing redox switches that not only perform specific mechanical movements but also drive important chemical reactions is important but a great challenge.Herein,we report a redox pair of cobalt species(Co^(Ⅲ)/Co^(...
Financial support from the Natural Science Foundation of Henan Province(No.222300420084);application research plan for key scientific research projects in colleges and universities of Henan Province(No.22A150056);Zhengzhou University(JC22261005),and the National Natural Science Foundation of China(No.21871237)are gratefully acknowledged.
Metal-and oxidant-free alkenyl C–H thiolation enabled by the azo group had been established for the modular synthesis of tetrasubstituted acyclic olefins.The reaction was performed under mild reaction conditions with...
supported by the National Natural Science Foundation of China(51861145401,21905136);the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions。
Developing methods to construct conjugated microporous polymers(CMPs)with desirable structures is a crucial undertaking.However,obtaining azo-CMPs with extended azaacene cores is immensely challenging.Herein,we disclo...
supported by the National Natural Science Foundation of China(No.21971126);the 111 Projects of China(No.B12015);the Frontiers Science Center for New Organic Matter,China(No.63181206).
Exploring new materials to manufacture proton-conducting membranes(PEMs)for fuel cells is highly significant.In this work,we fabricated two robust and highly crystalline porous covalent organic frameworks(COFs)via a s...