This work was supported by the National Natural Science Foundation of China(Nos.21831001,21571016,91122028);the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).
Two new belt-like borates Na_(4)[B_(9)O_(14)(OH)_(3)]·0.5H_(2)O(1)and Na_(5)[B_(9)O_(14)(OH)_(4)](2)have been synthesized under solvothermal conditions.Both compounds contain unprecedented B_(9)O_(16)(OH)_(n)^((n+5))...
supported by the National Natural Science Foundation of China (No. 21201056)。
Composite borate-phosphate compounds have always attracted much attention for their structure diversity and interesting properties.In this work,a new borate-phosphate Cs Na_(2)Lu_(2)(BO_(3))(PO_(4))_(2) (CNLBP) was fo...
supported by the Key Research Project of Frontier Science of CAS(QYZDB-SSW-JSC049);the National Natural Science Foundation of China(61875229,61835014 and 61922084);the National Key Research Project(2016YFB0402104);the Youth Innovation Promotion Association of CAS(2012305).
Introducing Pb2+cations with lone pair electrons in borates is efficient to form multiple crystalline forms.Here,we report two new compounds,α-Pb4B2O7 andβ-Pb4B6O13,which exhibit different crystal forms from the pre...
supported by the West Light Foundation of the CAS(2016-YJRC-2 and 2015 XBQN-B-11);the National Natural Science Foundation of China(51602341 and 91622107);the Natural Science Foundation of Xinjiang(2016D01B061);Tianshan Innovation Team Program(2018D14001);Key research project of Frontier Science of CAS(QYZDB-SSW-JSC049)
Three new complex borate compounds K7CaBi2B15O30, K7CaLa2B15 O30 and K7BaBi2B15O30 have been synthesized by the high-temperature solution method.K7CaLa2B15O30and K7CaBi2B15O30crystallize in the chiral trigonal space g...
Supported by the National Natural Science Foundation of China(No.20871012)
A new pentaborate, KNa2CdB5O(10), has been synthesized and its crystal structure was determined by single-crystal XRD method with the following crystal data: KNa2CdB5O(10), Pccn, a = 18.4555(13), b = 8.3040(10...
This work was supported by the National Natural Science Foundation of China (Grants 21773244, 21373222, and 21231006), the CAS Youth Innovation Promotion Association, and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant XDB20000000).
Lanthanide borates containing post transition metal main group elements, including Ga(Ⅲ), Ge(Ⅳ), Sb(Ⅴ) and Te(Ⅵ), as well as lanthanide salts of the oxyanions of lone pair cations, such as I(Ⅴ), Se(Ⅳ...
supported by the Special Foundation for Young Scientists of Beijing(No.2014000020124G009)
Cd-rich portion of the pseudo-binary system Cd3B2O6-Zn3B2O6 was investigated. A new cadmium zinc borate, Cd2.42Zn0.58B2O6, was synthesized successfully by a traditional solid-state reaction method. The compound crysta...
Supported by NSFC(21171166,21222102,21301172,21373220,21571178,21525104,51277091,51402296,51502288 and 51502290);Chunmiao Project of Haixi Institute of Chinese Academy of Sciences(CMZX-2015-003);NSF of Fujian Province(2015J01219,2015J05040)
A new boroantimonate K2SbB3O8 has been synthesized by high-temperature solidstate reactions, and its crystals have been obtained by the flux method. The crystal structure has been determined from single-crystal X-ray ...
the resources of Poznań Supercomputing and Networking Centre, grant No. 175
Terbium doped strontium-lanthanum borate, Sr3La2(BO3)4:Tb (SLB), was studied by semi-empirical computational ap- proaches using PM6 parametrization and the SPARKLE model for lanthanide(Ⅲ) (Ln(Ⅲ)) cations....
the Open Fund of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Chengdu University of Technology,China,the National Natural Science Foundation of China,the Specialized Research Fund for the Doctoral Program of Higher Education of China
The mean activity coefficients of KCI in a KCI-K2B407-H20 ternary system were experimentally determined at 308.15 K by the electromotive force measurement(EMF) via a battery cell without a liquid junction: K-ISEIKC...