support by a Hertha-Firnberg fellowship of the Austrian Science Fund (T962-N34).
Single hydration of the gas phase F^-+CH3I→CH3F reaction allows to probe solvent effects on a fundamental nucleophilic substitution reaction.At the same time,the addition of a solvent molecule opens alternative produ...
Supported by the National Natural Science Foundation of China(No10604012)
The Ca+CH3I→CaI+CH3 reaction system has been studied with the quasi-classical trajectory method on the extended Lond-Eyring-Polanyi-Sato(LEPS) potential energy surface. At collision energy Ecol=10.78 kJ/mol, the ...