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A concise formal stereoselective total synthesis of(-)-swainsonine被引量:1
《Chinese Chemical Letters》2014年第2期193-196,共4页Xiao-Gang Wang Ai-E Wang Pei-Qiang Huang 
financial support from the National Basic Research Program(973 Program)of China(No. 2010CB833200);the NSF of China(Nos.21332007,21072160);the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)of Ministry of Education,China for financial support
A short formal stereoselective synthesis of (-)-swainsonine (1) is described. Our synthesis started with the versatile building block (R)-3-benzyloxyglutarimide 5. Through controlled regioselective reduction, Le...
关键词:lndolizidines ALKALOIDS α-Amidoalkylation Building blocks Stereoselective synthesis 
Concise synthesis of two advanced intermediates for the asymmetric synthesis of polyhydroxylated indolizidine alkaloids被引量:2
《Science China Chemistry》2010年第9期1914-1920,共7页ZHENG Xiao1,2,ZHU WenFang1 & HUANG PeiQiang1 1Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China 2Key Laboratory of Synthetic Chemistry of Natural Substances Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China 
the National Natural Science Foundation of China (20832005);the National Basic Research Program (973 Program) of China (2010CB833200) for financial support
A concise five-step approach to indolizidinones 10 and 11,two advanced intermediates for the asymmetric synthesis of polyhydroxylated indolizidine alkaloids,has been developed by using N-Cbz pyrrolidin-2-yl pyridin-2-...
关键词:indolizidinone SAMARIUM DIIODIDE α-amidohydroxyalkylation TANDEM reaction CHIRAL building block 
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