We gratefully acknowledge financial support of this work by the National Natural Science Foundation of China (No. 21563025), Shihezi University Training Programme for Distinguished Youth Scholars (No. 2014ZRKXJQ05), and Start-Up Foundation for Young Scientists of Shihezi University (RCZX201408).
We developed a simple and efficient Cu(II)-catalyzed ligand-free oxidation of diarylmethanes and secondary alcohols using 70% ten-butyl hydroperoxide (TBHP) in water. A series of diarylmethanes were directly oxidi...
Copper(If) complex of a Schiff base ligand derived from pyrrolcarbaldehyde and o-phenylenediamine (H2L) has been synthesized and encapsulated in Y-zeolite matrix. The hybrid material has been characterized by elem...
Project supported by the Natural Science Foundation of Guangxi Province (No. 0339034) and the Science Research Foundation of Guangxi Univer-sities.
The reactions of transition metal salts with taurine 5-chlorosalicylaldelyde Schiff base gave two complexes [Ni(TCSSB)(H2O)3]旽2O (1) and [Cu(TCSSB)(H2O)2]2昜Cu(TCSSB)2]?H2O (2) (TCSSB=taurine-5-chlorosali- cylaldelyd...
Project supported by the National Natural Science Foundation of China (No. 20172040).
The first supramolecular adduct (H3O)2[Cu(H2O)4](SO4)2?(C30H30N20O10)?4(H2O) based on cucurbit[5]uril was synthesized and characterized by single crystal X-ray diffraction analysis. In the adduct, copper ion is coordi...
The synthesis and characterization of the copper(II) complex [Cu_2(OOCCH=C(CH_3)Fc)_3(phen)_2]ClO_4·2H_2O (1) are reported. The structure of the complex was determined by single-crystal X-ray analysis. The compound...
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .20175020),theFoundationofMinistryofEducationofChinaandtheGermanVolkswagenFoundation (No .I/ 770 72 )
A fluorescent aminoacid was designed for selective and sensitive detection of Cu(II) in aqueous solution. The designing of this Cu(II) fluorescent chemosensing molecule, N (1 naphthyl)~aminoacetic acid (NAA), w...
NationalNaturalScienceFoundationofTianjinEducationCommittee (No .972 0 2 )
With N,N′ bis(benzimidazol 2 yl methyl)amine as the ligand, a novel Cu(II) dinuclear complex was synthesized as a mimetic compound of superoxide dismutase (SOD). The complex was characterized with element ana...
ProjectsupportedbytheKeyProjectofEducationalAdministrationofShandongProvince (No .J0 1C0 5 )andtheOutstandingAdult YoungScien tificResearchEncouragingFoundationofShandongProvince (No .O1BS18)
The structures of [Cu(S_2CN(CH_2)_4)_2] (1) and [Zn_2(S_2CN-(CH_2)_4)_4] (2) have been determined by X-ray crystallography analysis. They are all isomorphous and triclinic, space group of P1, with Z=1. The lattice p...
ProjectsupportedbytheNaturalScienceFoundationofGuangdongProvince (No .0 10 338)andtheNaturalScienceFoundationofEducationDe partmentofGuangdongProvince (No .2 0 0 0 70 )
The ternary Cu(II) complex with 2,2′-bipyridyl (bipy) and L-methioninate (L-Met) has been synthesized and characterized by elemental analysis, molar conductivity, UV-Vis spectra, IR spectra and pH-potentiometric titr...
theNaturalScienceFoundationofEducationCommissionofJiangsuProvince (No .0 1KJB15 0 0 10 )
A novel supramolecular complex {[Cu(II)(en) 2·H 2O]· [Cu(I) 2(CN) 4]} n (en=ethylenediamine), in which the cyanide-bridged Cu(I) forms the honeycomb-like skeleton host and the Cu(II) complex ion [Cu(en)...