CU(II)

作品数:163被引量:351H指数:8
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相关领域:理学更多>>
相关作者:沈海民董育斌佘远斌涂涛刘小兰更多>>
相关机构:浙江工业大学湖南大学中国科学院兰州交通大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划国家科技支撑计划河南省自然科学基金更多>>
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Cu(II)-Catalyzed Ligand-Free Oxidation of Diarylmethanes and Second Alcohols in Water被引量:5
《Chinese Journal of Chemistry》2017年第9期1391-1395,共5页Jianglong Wu Yan Liu Xiaowei Ma Ping Liu Chengzhi Gu Bin Dai 
We gratefully acknowledge financial support of this work by the National Natural Science Foundation of China (No. 21563025), Shihezi University Training Programme for Distinguished Youth Scholars (No. 2014ZRKXJQ05), and Start-Up Foundation for Young Scientists of Shihezi University (RCZX201408).
We developed a simple and efficient Cu(II)-catalyzed ligand-free oxidation of diarylmethanes and secondary alcohols using 70% ten-butyl hydroperoxide (TBHP) in water. A series of diarylmethanes were directly oxidi...
关键词:Cu-catalyzed OXIDATION diarylmethane LIGAND-FREE WATER 
Heterogeneous Green Catalyst for Oxidation of Cyclohexene and Cyclooctene with Hydrogen Peroxide in the Presence of Host (Nanocavity of Y-zeolite)/Guest (N4-Cu(II) Schiff Base Complex) Nanocomposite Material
《Chinese Journal of Chemistry》2011年第11期2439-2444,共6页Lashanizadegan, Maryam Rayati, Saeed Dejparvar Derakhshan, Zeinab 
Copper(If) complex of a Schiff base ligand derived from pyrrolcarbaldehyde and o-phenylenediamine (H2L) has been synthesized and encapsulated in Y-zeolite matrix. The hybrid material has been characterized by elem...
关键词:Schiff base copper zeolite hydrogen peroxide catalyst 
Synthesis, Crystal Structure, Properties and Thermoanalysis of Complexes of Cu(II) and Ni(II) with Taurine-5-chlorosalicylaldelyde Schiff Base
《Chinese Journal of Chemistry》2004年第11期1303-1307,共5页张淑华 蒋毅民 周忠远 
Project supported by the Natural Science Foundation of Guangxi Province (No. 0339034) and the Science Research Foundation of Guangxi Univer-sities.
The reactions of transition metal salts with taurine 5-chlorosalicylaldelyde Schiff base gave two complexes [Ni(TCSSB)(H2O)3]旽2O (1) and [Cu(TCSSB)(H2O)2]2昜Cu(TCSSB)2]?H2O (2) (TCSSB=taurine-5-chlorosali- cylaldelyd...
关键词:molecular structure taurine-5-chlorosalicylaldelyde Schiff base copper(II) nickel(II) TG-DTG 
Synthesis and Crystal Structure of Macrocyclic Cavitand Cu-curbit[5]uril and Its Supramolecular Adduct with Cu(II)被引量:2
《Chinese Journal of Chemistry》2004年第10期1208-1210,共3页刘思敏 黄子祥 吴晓军 梁峰 吴成泰 
Project supported by the National Natural Science Foundation of China (No. 20172040).
The first supramolecular adduct (H3O)2[Cu(H2O)4](SO4)2?(C30H30N20O10)?4(H2O) based on cucurbit[5]uril was synthesized and characterized by single crystal X-ray diffraction analysis. In the adduct, copper ion is coordi...
关键词:CUCURBIT[5]URIL crystal structure supramolecular adduct 
Preparation,Crystal Structure and Properties of a Pentametallic 3-Ferrocenyl-2-crotonic acid-Bridged Copper(II) Complex
《Chinese Journal of Chemistry》2003年第11期1461-1465,共5页杨家祥 张泽 吴杰颖 田玉鹏 刘清亮 FUN Hoong Kun USMAN Anwar 许志强 LAURENCE K.Thompson 
ProjectsupportedbytheMajorStateBasicResearchDevelopmentProgram (No .G19980 614 0 2 ) ,theNationalNaturalScienceFoundationofChina (Nos .2 0 0 710 0 1,5 0 2 72 0 0 1) ,theNaturalScienceFoundationofAnhuiProvince (No .0 3 0 44 70 1)andtheMalaysianGovernmenta
The synthesis and characterization of the copper(II) complex [Cu_2(OOCCH=C(CH_3)Fc)_3(phen)_2]ClO_4·2H_2O (1) are reported. The structure of the complex was determined by single-crystal X-ray analysis. The compound...
关键词:crystal structure Cu(II) complex magnetic susceptibility 
A Novel Fluorescent Aminoacid Designed for Fluorometric Detection of Cu(II)
《Chinese Journal of Chemistry》2003年第10期1335-1338,共4页孙向英 温珍昌 江云宝 
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .20175020),theFoundationofMinistryofEducationofChinaandtheGermanVolkswagenFoundation (No .I/ 770 72 )
A fluorescent aminoacid was designed for selective and sensitive detection of Cu(II) in aqueous solution. The designing of this Cu(II) fluorescent chemosensing molecule, N (1 naphthyl)~aminoacetic acid (NAA), w...
关键词:N (1 naphthyl)aminoacetic acid fluorescence quenching CU(II) electron transfer 
Synthesis and Structure of a Novel Copper(II) Dinuclear Complex with 4,4′-Dipyridyl as the Bridge
《Chinese Journal of Chemistry》2003年第8期1047-1053,共7页刘小兰 赵茹 刘晓红 岳俊杰 尹宇新 孙云 张欣 
NationalNaturalScienceFoundationofTianjinEducationCommittee (No .972 0 2 )
With N,N′ bis(benzimidazol 2 yl methyl)amine as the ligand, a novel Cu(II) dinuclear complex was synthesized as a mimetic compound of superoxide dismutase (SOD). The complex was characterized with element ana...
关键词:N N′    bis(benzimidazol  2  yl  methyl)amine CU(II) three  dimensional network complex crystal structure quantum chemistry computation biological activity 
Crystal Structures and Characterizations of Bis(pyrrolidinedithiocarbamato) Cu(II) and Zn(II) Complexes
《Chinese Journal of Chemistry》2003年第1期50-55,共6页建方方 薛婷 焦奎 张书圣 
ProjectsupportedbytheKeyProjectofEducationalAdministrationofShandongProvince (No .J0 1C0 5 )andtheOutstandingAdult YoungScien tificResearchEncouragingFoundationofShandongProvince (No .O1BS18)
The structures of [Cu(S_2CN(CH_2)_4)_2] (1) and [Zn_2(S_2CN-(CH_2)_4)_4] (2) have been determined by X-ray crystallography analysis. They are all isomorphous and triclinic, space group of P1, with Z=1. The lattice p...
关键词:X-ray dithiocarbamate(dtc) thermal gravity(TG) copper(II) and zinc(II) complexes 
A Novel Cu(II) Complex with 2,2′-Bipyridyl and L-Methioninate──Synthesis, Characterization, Molecular Structure and Stability被引量:5
《Chinese Journal of Chemistry》2003年第1期44-49,共6页乐学义 童明良 付银莲 计亮年 
ProjectsupportedbytheNaturalScienceFoundationofGuangdongProvince (No .0 10 338)andtheNaturalScienceFoundationofEducationDe partmentofGuangdongProvince (No .2 0 0 0 70 )
The ternary Cu(II) complex with 2,2′-bipyridyl (bipy) and L-methioninate (L-Met) has been synthesized and characterized by elemental analysis, molar conductivity, UV-Vis spectra, IR spectra and pH-potentiometric titr...
关键词:BIPYRIDYL L-methioninate copper(II) complex crystal structure 
A Novel Self-assembled Supramolecular Complex {[Cu(II)(en)_2·[JP]H_2O] [Cu(I)_2(CN)_4]}_n with Honeycomb-like Structure and Its Adsorption Properties被引量:3
《Chinese Journal of Chemistry》2002年第12期1472-1476,1459,共6页沈小平 邹建忠 李宝龙 胡怀民 徐正 
theNaturalScienceFoundationofEducationCommissionofJiangsuProvince (No .0 1KJB15 0 0 10 )
A novel supramolecular complex {[Cu(II)(en) 2·H 2O]· [Cu(I) 2(CN) 4]} n (en=ethylenediamine), in which the cyanide-bridged Cu(I) forms the honeycomb-like skeleton host and the Cu(II) complex ion [Cu(en)...
关键词:crystal structure CYANO-BRIDGED copper complex adsorption properties supramolecular complex 
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