HYDRATES

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Uranyl oxamate hydrates: hydrothermal synthesis, crystal structure, photophysical properties, and selective crystallization
《Science China Chemistry》2016年第6期740-745,共6页Yubo Shu Weisheng Liu 
supported by the National Natural Science Foundation of China (21431002);the Specialized Research Fund for the Doctoral Program of Higher Education (20110211130002)
Presented here are two isostructural uranyl coordination polymers [UOe(EDO)(H2O)]· H2O (1) and [UO2(BDO)(H2O)]-2H2O (2) (EDO2---ethylene-1,2-dioxamate; BDO2 =butylene-1,2-dioxamate) with identical stepw...
关键词:uranium oxamate hydrothermal synthesis PHOTOPHYSICS selective crystallization 
Low temperature heat capacities and thermodynamic properties of rare earth triisothiocyanate hydrates——Pr(NCS)_3· 7H_2O and Nd(NCS)_3· 7H_2O
《Science China Chemistry》1996年第3期276-284,共9页谭志诚 Matsuo Takasuke Suga Hiroshi 张志英 尹敬执 蒋本杲 孙同山 
Project supported by the National Natural Science Foundation of China
Heat capacities of Pr(NCS)3·7H2O and Nd(NCS)3· 7H2O haw been measured from 13 to 300 K by using a fully automated adiabatic calorimeter. Schottky anomaly was observed for Pr(NCS)3·7H2O below 50 K. The polynomial eq...
关键词:heat capacity thermodynamic functions rare earth Pr(NCS)3·7H2O Nd(NCS)3·7H2O. 
FOURIER TRANSFORM FAR INFRARED SPECTRA AND NORMAL COORDINATE ANALYSIS OF FIFTEEN RARE-EARTH OXALATE HYDRATES
《Science China Chemistry》1989年第3期293-302,共10页王秀珍 吴瑾光 施鼐 金天柱 徐光宪 
The Fourier transform far infrared spectra of oxalate hydrates of whole rare-earth series except Pm and Sc are investigated in the range of 100-400 cm^(-1). The assignment of vibrational frequencies is made on the bas...
关键词:Fourier transform infrared spectroscopy (FTIR) normal coordinate analysis RARE-EARTH OXALATES or LANTHANIDE OXALATES far IR spectra. 
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