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作品数：164被引量：255H指数：8
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相关作者：王彦广钱荣郭寅龙兰凤英甘利华更多>>
相关机构：中国科学院浙江大学湖南大学中国农业科学院兰州兽医研究所更多>>
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Palladium-catalyzed carbonylation of activated alkyl halides via radical intermediates
《Industrial Chemistry & Materials》2024年第2期276-283,共8页Zhi-Peng Bao Xiao-Feng Wu 
financial support from DICP and K.C.Wong Education Foundation(GJTD-2020-08).
Palladium-catalyzed carbonylation is an efficient approach to prepare carbonyl-containing compounds with high atomic economy in synthetic organic chemistry.However,in comparison with aryl halides,carbonylation of alky...
关键词：Carbonyl group Palladium catalysis CARBONYLATION Activated alkyl halides Radical intermediates 
Regulating the radical intermediates by conjugated units in covalent organic frameworks for optimized lithium ion storage被引量：1
《Journal of Energy Chemistry》2022年第6期428-433,I0012,共7页Shuai Gu Xiaoxia Ma Jingjing Chen Rui Hao Zhiqiang Wang Ning Qin Wei Zheng Qingmeng Gan Wen Luo Muqing Li Zhiqiang Li Kemeng Liao Hao Guo Guiyu Liu Kaili Zhang Zhouguang Lu 
supports from the Basic Research Project of the Science and Technology Innovation Commission of Shenzhen (No. JCYJ20200109141640095);the Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (No. ZDSYS20200421111401738);the Leading Talents of Guangdong Province Program (No. 2016LJ06C536);the GuangdongHong Kong-Macao Joint Laboratory (No. 2019B121205001);the National Natural Science Foundation of China (No. 21875097);the support from the Hong Kong Research Grants Council (Project number CityU 11218420)。
Organic active units often transform into radical intermediates during the redox processes but exhibit poor cycling stability due to the uncontrollable redox of the radicals. Herein, we report a facile and efficient s...
关键词：Organic electrodes Radical intermediates Covalent organic frameworks 
Photoredox Ni-Catalyzed Selective Coupling of Organic Halides and Oxalates to Esters via Alkoxycarbonyl Radical Intermediates
《CCS Chemistry》2022年第4期1326-1336,共11页Wen-Duo Li Yi-Qian Jiang Yan-Lin Li Ji-Bao Xia 
the financial support from the NSFC of China(21772208 and 21633013);Natural Science Foundation of Jiangsu Province(BK20201183);the Key Research Program of Frontier Sciences of Chinese Academy of Sciences(QYZDJSSW-SLH051).
A new approach for radical cross coupling of organic halides and oxalates toward esters has been developed via photoredox nickel dual catalysis.This method has been demonstrated for transformation of a wide range of a...
关键词：photoredox catalysis nickel catalysis ester alkoxycarbonyl radical alkoxy carbonylation 
C–F bond functionalizations of trifluoromethyl groups via radical intermediates被引量：1
《Chinese Chemical Letters》2022年第3期1193-1198,共6页Tesfaye Tebeka Simur Tian Ye You-Jie Yu Feng-Lian Zhang Yi-Feng Wang 
National Natural Science Foundation of China (No.21971226);the Fundamental Research Funds for the Central Universities (No. WK2060000017) for financial support。
Selective functionalization of C-F bonds in trifluoromethyl groups has recently received a growing interest, as it offers atom- and step-economic pathways to access highly valuable mono- and difluoroalkyl-substituted ...
关键词：C–F bond functionalizations Radical intermediates Trifluoromethyl groups Difluorinated compounds Monofluorinated compounds 
O2-Oxidation of Cyanomethylene Radical:Infrared Identification of Criegee Intermediates syn-and anti-NCC(H)OO被引量：1
《Chinese Journal of Chemical Physics》2020年第2期151-159,I0002,I0018-I0038,共31页Bo Lu Yuan-yuan Qin Chao Song Wei-yu Qian Li-na Wang Xiao-qing Zeng 
supported by the National Natural Science Foundation of China (No.21673147).
Cyanomethylene radical(HCCN)is an important intermediate in the nitrile chemistry in both the earth’s and the Titan’s atmosphere.Despite that the mechanism for the oxidation of HCCN has been already computationally ...
关键词：Methylene radicals Criegee intermediates Oxidation PHOTOCHEMISTRY IR spectroscope 
Intrinsic chemiluminescence production from the degradation of haloaromatic pollutants during environmentally-friendly advanced oxidation processes:Mechanism,structure-activity relationship and potential applications被引量：4
《Journal of Environmental Sciences》2017年第12期68-83,共16页Benzhan Zhu Chen Shen Huiying Gao Liya Zhu Jie Shao Li Mao 
supported by the Strategic Priority Research Program of CAS(No.XDB01020300);NSF China Grants(Nos.21577149,21477139,21237005 and 21321004);NIH Grants(Nos.ES11497,RR01008 and ES00210)
The ubiquitous distribution of halogenated aromatic compounds（XAr） coupled with their carcinogenicity has raised public concerns on their potential risks to both human health and the ecosystem. Recently, advanced ox...
关键词：Halogenated phenols Halogenated quinoid intermediates Semiquinone radical Hydroxyl radicals Fenton reaction Chemiluminescene method 
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