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Syntheses, structures and magnetic properties of three Co(Ⅱ)coordination architectures based on a flexible multidentate carboxylate ligand and different N-donor ligands被引量：5
《Science China Chemistry》2013年第12期1693-1700,共8页TIAN Dan LIU SuiJun ZHANG DaShuai CHANG Ze HU TongLiang BU XianHe 
supported by the National Natural Science Foundation of China(21031002,51073079 and 21003078);Natural Science Foundation of Tianjin,China(11JCYBJC04100)
Three new cobalt complexes, {[Co5（tci）2（bimb）3（μ3-O）2（H2O）2]·3DMF·4H2O}n（1）, {[Co3（tci）2（bib）]·2DMF·2H2O}n （2） and {[Co（Htci）（bpea）0.5]-H2O}n （3） （H3tci = tris（2-carboxyethyl）isocyanurate...
关键词：Coordination polymers cobalt clusters TOPOLOGY magnetic properties 
Di- and tetranuclear heterometallic CuⅡ-LnⅢ complexes (Ln = Gd and Dy): Synthesis, structure and magnetic properties被引量：2
《Science China Chemistry》2012年第6期934-941,共8页ZHANG ZeMin GUO FuSheng GUO PengHu LIU JunLiang NI ZhaoPing TONG MingLiang 
supported by the National Natural Science Foundation of China (91122032, 90922009, 21121061);the National Basic Research Program of China (2012CB821704)
Four 3d-4f heterometallic complexes, [CuⅡ-LnⅢ(bpt)2(NO3)3(MeOH)] (Ln = Gd, 1; Dy, 2; bptH = 3,5-bis(pyrid-2-yl)-l,2,4- triazole), [CuⅡ-LnⅢ(μ-OH)2(bpt)4C14 (H2O)2]·6H2O (Ln = Gd, 3; Dy, 4), have been synthesized ...
关键词：heterometallic complexes copper LANTHANIDES triazolate X-ray crystallography magnetic properties 
An inverted triplesalen ligand by a convergent synthesis and its influence on trinuclear Fe_3~Ⅲ complexes被引量：1
《Science China Chemistry》2012年第6期951-966,共16页FELDSCHER Bastian KRICKEMEYER Erich MOSELAGE Marc THEIL Hubert HOEKE Veronika KAISER Yvonne STAMMLER Anja BGGE Hartmut GLASER Thorsten 
supported by the Deutsche Forschungsgemeinschaft(FOR945 ‘Nanomagnets: from Synthesis via Interactions with Surfaces to Function’);the Fonds der Chemischen Industrie;Bielefeld University
The inverted triplesalen ligand H6feldMe has been synthesized from 2,4,6-triformyl-phloroglucinol and a ketimine salen half-unit in a convergent synthesis. NMR, IR, and UV-vis spectroscopy reveal that this ligand is n...
关键词：magnetic properties iron complexes SPIN-POLARIZATION triplesalen 
Cyanide-bridged complexes based on dinuclear Cu(Ⅱ)-M(Ⅱ) [M=Pb and Cu] building blocks: Synthesis, crystal structures and magnetic properties被引量：3
《Science China Chemistry》2012年第6期978-986,共9页WANG HaiLong WANG Kang CAO Wei BAI Ming BIANYongZhong JIANG JianZhuang 
financially supported by the National Natural Science Foundation of China;Ministry of Education of China;Beijing Municipal Commission of Education;Fundamental Research Funds for the Central Universities
Four cyanide-bridged heterometallic complexes { [CuPb（L1）][FenI（bpb）（CN）2] }2-（C104）2.2H20.2CH3CN （1）, { [CuPb（LI）]2[FeII （CN）6]（HzO）z}＇10H20 （2）, {[Cu2（L2）][Fent（bpb）（CN）2]2}＇2H20＇2CH3OH （...
关键词：cyanide-bridged complex crystal structures magnetic properties 
Cyanido-bridged one-dimensional systems assembled from [Re~ⅣCl_4(CN)_2]_(2-) and [M~Ⅱ(cyclam)]^(2+) (M=Ni,Cu) precursors
《Science China Chemistry》2012年第6期1004-1011,1192-1197,共8页BHOWMICK Indrani HARRIS T. David DECHAMBENOIT Pierre HILLARD Elizabeth A. PICHON Cline JEON Ie-Rang CLéRAC Rodolphe 
supported by the Centre National de la Recherche Scientifique (CNRS);the University of Bordeaux;the Conseil Régional d'Aqui-taine;GIS Advanced Materials in Aquitaine (COMET Project);the ANR(NT09_469563, AC-MA Gnets project);the Erasmus Mundus Mobilitywith Asia (EMMA) program (External Cooperation Window-ASIE) for the PhD fellowship of I. B.
Three new cyanido-bridged heterometallic ReIVNin and ReIVCu one-dimensional systems were synthesized and extensively characterized both structurally and magnetically. Single-crystal X-ray diffraction analysis revealed...
关键词：molecular magnets cyanido-based materials crystal structure magnetic properties 
Solvothermal preparation of iron phosphonate cages
《Science China Chemistry》2012年第6期910-913,共4页WINPENNY Richard E. P. 
financially supported by Marie Curie International Incoming Fellowship (E.C. Contract No: PIIF-GA-2008-219588);the starting fund of Xi’an Jiaotong University (to YZZ);the Engineering and Physical Science Research Council (UK);the Royal Society for a Wolfson Merit Award (to REPW)
Three new iron（Ⅲ） phosphonate cage-like complexes with [Fe4], [Feg] and [Fe14] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic i...
关键词：POLYNUCLEAR IRON coordination PHOSPHONATE magnetic properties 
An unexpected tetranuclear Li_2Cr_2 trimethylsilylacetylide complex bridged by two μ_3-pyrazolates
《Science China Chemistry》2012年第6期914-917,共4页WANG Feng CAO Li LIAO HongLin JIANG Jun JIA XiaoLu GAO Qian LI DongFeng 
financially supported by the National Natural Science Foundation of China (20801022, 21172084);the Program for New Century Excellent Talents in University of China (NCET-10-0406);the Program for Changjiang Scholars and Innovative Research Team in University (IRT0953);Self-Determined Research Funds of CCNU from the Col- leges' Basic Research and Operation of MOE (CCNU09A02002, CCNU11C01002)
A tetranuclear Li2Cr2 acetylide precursor complex, [Li(Tp)crm(c=CSiMe3)2(/,t3-pz)]2· (n-pentane)2 (Tp = hydridotris(pyra- zolyl)borate, pz = pyrazolate) (1) has been synthesized and characterized. The X-ray structure...
关键词：acetylide complex SYNTHESIS X-ray structure magnetic properties 
Chiral cyanide-bridged 1D Fe~Ⅲ-Mn~Ⅲ heterobimetallic chains: Synthesis, structures and magnetic properties被引量：4
《Science China Chemistry》2012年第6期1022-1030,共9页YAO MinXia ZHENG Qi GAO Feng LI YiZhi ZUO JingLin 
financially supported by the Major State Basic Research Development Program (2011CB808704);the National Natural Science Foundation of China (91022031)
Two couples of enantiomerically pure chiral cyano-bridged heterobimetallic one-dimensional (1D) chain complexes: [Mn((R,R)-Salphen)Fe(Tp)(CN)3],, (1) and [Mn((S,S)-Salphen)Te(Tp)(CN)3]n (2) (Salphen = N,N'-l,2-dipheny...
关键词：chiral complexes cyanide ligands chain compounds crystal structures magnetic properties 
Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties
《Science China Chemistry》2012年第6期1055-1063,共9页WANG XinYi WANG ZheMing GAO Song 
support from the National Natural Science Foundation of China (21101093, 90922033);the Natural Science Foundation of Jiangsu Province (BK2011548)
Detailed studies of the structures, magnetic properties and photodimerization of a series of formato-bridged MOFs with the general formula M2(HCOO)3(4,4'-bpe)3(H20)3(X) (4,4'-bpe = 4,4'-bipyridylethylene, M = Mn (l-X-...
关键词：metal formate SPIN-FLOP magnetic phase diagram PHOTODIMERIZATION 
Three new Cu(Ⅱ)-Ln(Ⅲ) heterometallic coordination polymers constructed from quinolinic acid and nicotinic acid: Synthesis, structures, and magnetic properties
《Science China Chemistry》2012年第6期1064-1072,共9页LIU SuiJun SONG WeiChao XUE Li HAN SongDe ZENG YongFei WANG LiFu BU XianHe 
financially supported by the National Natural Science Foundation of China (21031002, 51073079, 20801029)
Three new Cu（Ⅱ）-Ln（Ⅲ） heterometallic coordination polymers based on two N-heterocyclic carboxylic ligands, {[LnCu（LI）2（L2）（H2O）2]· mH20},, （Ln = La（1）, Nd（2）, Gd（3）, m = 2 （for 1）, 1 （for 2, 3）...
关键词：Cu（Ⅱ）-Ln（Ⅲ） coordination polymers metal oxides magnetic properties 
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