The State Key Basic Research and Development Plan(G1998010100);the National Natural Science Foundation of China(29733090,29973047,39970177)
Six model compounds have been synthesized and used for probing the structural features of the Mn cluster in oxygen_evolving complex (OEC) of photosystem Ⅱ (PSⅡ). The model compounds contain Mn 2(μ_O) 2 and μ_O_...