Synthesis and Cleavage Studies of a 1,2-Dioxolane-type Peroxide  

作　　者：刘鹤华 金红霞 伍贻康 

机构地区：[1]State Key Laboratory of Bio-organic & Natural Products Chemistry,Shanghai Institute of Organic Chemistry, Chi-nese Academy of Sciences,Shanghai 200032,China

出　　处：《Chinese Journal of Chemistry》2004年第9期1029-1033,共5页中国化学（英文版）

基　　金：the National Natural Science Foundation (Nos. 20025207, 20272071, 20372075 and 20321202), the Qinghaosu Science and Technology Foundation, the Chinese Academy of Sciences (KGCX2-SW-209) and the Major State Basic Research Develop

摘　　要：A [1,2]dioxolane-type peroxide was synthesized and tested for its cleavage behavior with Fe2+-cysteinate as a simple model of biological redox species. No S-alkylation product was observed.A [1,2]dioxolane-type peroxide was synthesized and tested for its cleavage behavior with Fe2+-cysteinate as a simple model of biological redox species. No S-alkylation product was observed.

关 键 词：cyclic peroxide ARTEMISININ free radical CLEAVAGE mechanism 

分 类 号：O621[理学—有机化学]