一种基于三苯胺类光生酸剂的制备与表征  

Synthesis and Indication of Photoacid Generator Derived From Triphenylamine

作　　者：韩元利[1] 王文广[1] 蒲嘉陵[1] 

机构地区：[1]北京印刷学院印刷包装材料与技术北京市重点实验室,北京102600

出　　处：《信息记录材料》2006年第6期37-38,42,共3页Information Recording Materials

摘　　要：成功合成了1种以三苯胺为主体的硫盐光生酸剂,其结构经1HNMR、IR分析确证,并对其物性进行了基本考察,有较高的热分解温度和在常用有机溶剂中有较好的溶解性。并考察了其在相同浓度、相同光强、相同曝光波长(405 nm)下在3种不同溶剂(乙腈、四氢呋喃、二氯甲烷)中的分解及产酸性能,计算出分解量子产率和产酸效率。A sulfonium salt as Photoacid Generator has been suoeessfully synthesized. Its structure was oonfirmed by ^1HNMR, IR and some physical datas were acquired, for example, high thermo-deeomposition temperature and can dissolve into organic solvents well. At the same time, its photo-decomposition and acid-forming performance under irradiation at 405 nm,in three solvents （acetonitrile, THF, CH2Cl2 ） were evaluated by the method established in our laboratory.

关 键 词：光生酸剂 硫捞盐 产酸性能 

分 类 号：TS802[轻工技术与工程]