表面接枝高分子季铵盐的纳米SiO_2应用于抗菌塑料的制备  

Preparation of Antimicrobial Plastics Containing Nano-meter SiO_2 Grafted High-molecular Quaternary Ammonium Salt

作　　者：吴远根[1] 王广莉[2] 张难[1] 佟会[1] 王啸[1] 邱树毅[1] 

机构地区：[1]贵州省发酵工程与生物制药重点实验室,贵州贵阳550003 [2]贵州大学化学工程学院,贵州贵阳550003

出　　处：《塑料工业》2007年第2期50-53,56,共5页China Plastics Industry

基　　金：国家自然科学基金(50363001);国家"863"计划基金(2003AA33X080);贵州省自然科学基金(20033082);贵州省知工办人才基金;贵州省教育厅基金;贵州遵义碱厂横向合作项目

摘　　要：对表面接枝高分子季铵盐的纳米SiO2粉体进行检测,结果表明其热稳定性良好,对细菌的抗菌效果显著,抗菌性能与市售载银无机抗菌剂相当。将其添加到不同树脂中制备抗菌塑料,抗菌检测结果表明,用PE和PVC作为基材树脂制备的抗菌塑料的抗菌效果十分显著,其用于制备抗菌PE的最佳添加质量分数为2%。对制备的抗菌PE分别进行了自然条件放置和人工加速老化处理,抗菌检测结果表明,该塑料具备了良好的抗菌长效性和稳定性。The nano-meter SiO2 surface grafted by high-molecular-weight quaternary ammonium salt was tested, and the results showed the grafted nano-meter SiO2 had good thermal stability and superior antibacterial action, which was about the same with that of the commercial Ag^ ＋ -containing inorganic antimierobial materials. The antimierobial nano-meter SiO2 was applied to the preparation of antimierobial plastics. The result of the antimierobial tests showed the microbicidal action of antimierobial plastics made from PE and PVC was superior. The optimum addition of the antimierobial nano-meter SiO2 for the preparation of antimierobial PE was 2%. The prepared PE was treated by means of accelerated aging and placement on natural conditions respectively, and the results showed the antimierobial PE had good long-time bactericidal action and mierobieidal stability.

关 键 词：纳米SIO2 高分子 季铵盐 表面接枝 抗菌塑料 长效性 

分 类 号：TQ320.7[化学工程—合成树脂塑料工业]