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作 者:江少群[1] 马欣新[1] 唐光泽[1] 孙明仁[1] 王刚[1]
机构地区:[1]哈尔滨工业大学材料科学与工程学院,哈尔滨150001
出 处:《中国表面工程》2008年第2期11-14,共4页China Surface Engineering
基 金:新世纪优秀人才支持计划资助
摘 要:采用直流磁控溅射技术,在不同的O2/(O2+Ar)体积比条件下于Si(100)基片上沉积La–Sr–Mn–O薄膜,结合扫描电子显微分析研究了O2/(O2+Ar)比对薄膜沉积速率的影响。结果表明:薄膜厚度均匀,O2/(O2+Ar)比是影响薄膜沉积速率的重要因素。基体温度和溅射气压较高时,薄膜沉积速率随O2/(O2+Ar)比增加呈抛物线规律下降,O2/(O2+Ar)比由4.4%增加到45.6%,沉积速率减小量可达52.8%;基体温度和溅射气压较低时,薄膜沉积速率随O2/(O2+Ar)比增大呈指数规律下降。薄膜沉积速率下降是由于被溅射原子/离子与氧原子/离子的碰撞几率随氧气含量增加而增大,从而降低了被溅射粒子的能量,使到达基片的粒子数减少。The La-Sr-Mn-O thin films were deposited on Si(100) substrate by DC magnetron sputtering with different O2/(O2+Ar) ratio. The effect of O2/(O2+Ar) ratio on the deposition rate of the films was studied using SEM (scanning electron microscopy) analysis. The results showed that the film thickness was homogeneous and the O2/(O2+Ar) ratio displayed an important effect on deposition rate. The deposition rate of films grown at higher substrate temperature and sputtering pressure decreased in parabolic relation with the increasing of O2/(O2+Ar) ratio. It decreased 52.8% when O2/(O2+Ar) ratio increased from 4.4% to 45.6%. The deposition rate of films grown at lower substrate temperature and sputtering pressure decreased in exponential relation with the increase of O2/(O2+Ar) ratio. The increase of oxygen content increased the collision probability between oxygen atoms/ions and sputtered atoms/ions, which decreased the kinetic energy of sputtered atoms/ions. Then the number of sputtered atoms/ions arriving at substrate decreased, which resulted in the reduction of deposition rate.
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