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作 者:刘俊峰[1] 吴顺华[1,2] 王爽[1] 陈志兵[1] 王小勇[1]
机构地区:[1]天津大学电信学院,天津300072 [2]天津大学先进陶瓷与加工技术教育部重点实验室,天津300072
出 处:《稀有金属材料与工程》2008年第A01期355-358,共4页Rare Metal Materials and Engineering
基 金:天津市自然科学基金资助项目(06YFJMJC01000)
摘 要:研究了BNT(BaO-Nd_2O_3-TiO_2)陶瓷中添加BZB(B_2O_3-ZnO-Bi_2O_3)玻璃后对烧结温度以及介电性能的影响。经过测试玻璃—陶瓷混合体的微波介质性能,发现该玻璃能将烧结温度降低到900℃或者更低。这是由于低软化点的BZB玻璃和高熔点的BNT相互作用,使得BNT和BZB之间润湿良好。BNT-BZB在900℃下烧结,具有优良的介电性能,表现为:介电常数ε约为75,损耗tanδ约为5‰,温度系数TCC约为0.5%,绝缘电阻大于10^(11)Ω。结果表明这种体系可以用来作为高频应用的低温共烧材料。The effect of addition of B2O3-ZnO-Bi2O3 (BZB) glass on the sintering temperature and the dielectric properties of the BNT (BaO-Nd2O3-TiO2) ceramics was studied. The microwave dielectric properties of the glass-ceramic composite were evaluated. The BZB glass enabled the reduction of the sintering temperature to below 900℃. This was due to the low-softening-point of the BZB glass, which, in reaction with the high-melting-point phase of BNT, provided good wetting between BZB and BNT. The composite sintered at 900℃ exhibited excellent dielectric properties of ε=75, tanδ = 5‰ and TCC =0.5%. Therefore, the composite has the potential to use in low temperature co-firing of the ceramic compositions for their high frequency application.
关 键 词:低温共烧陶瓷 BaO-Nd2O3-TiO2系统陶瓷 介电性能
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