β-二羰基化合物的电解氧化偶联反应  

The ElectrolyticOxidative Coupling Reaction of βDicarbonyl Compounds

作　　者：朱洪友[1] 张成敏[1] 刘复初[1] 

机构地区：[1]云南大学化学系

出　　处：《应用化学》1998年第2期94-96,共3页Chinese Journal of Applied Chemistry

基　　金：云南省应用基础研究基金

摘　　要：β┐二羰基化合物的电解氧化偶联反应朱洪友张成敏刘复初＊（云南大学化学系昆明６５００９１）关键词β－二羰基化合物，电氧化，偶联反应１９９７－０６－０４收稿，１９９７－１２－１０修回云南省应用基础研究基金资助项目在有机合成上，β－二羰基化合物的偶联是形成...The indirect electrolytic oxidative coupling reaction of some activated methylene compounds was studied by using KINaI as the indirect electrolyte and acetone as solvent. The results showed that this oxidative system was suitable for βdicarbonyl compounds having acidity of pK=9￣13 under proper conditions to give symmetric multifunctional products in satisfactory yields.

关 键 词：β-二羰基 电氧化 偶联 二羰基化合物 

分 类 号：O621.261[理学—有机化学]