食品接触材料中双酚类物质迁移检测方法研究  

Determination of Bisphenol-type Contaminants from Food Contacting Materials

作　　者：陈志锋[1] 刘晓华[2] 孙利[1] 

机构地区：[1]中国检验检疫科学研究院,北京100123 [2]北京市劳动保护科学研究所,北京100054

出　　处：《包装工程》2009年第12期40-43,共4页Packaging Engineering

基　　金：国家质检总局科研课题(2006IK111)

摘　　要：选用去离子水、3%乙酸溶液、10%乙醇溶液和精制橄榄油作为4种食品模拟物,开展了食品接触材料中双酚A,双酚A二甘氨酸醚、双酚F二甘氨酸醚及其衍生物等9种双酚类物质迁移检测方法研究。目标分析物采用反相液相色谱柱分离,荧光检测器进行检测。水基食品模拟物(去离子水、3%乙酸溶液、10%乙醇溶液)中的目标分析物可直接进样,精制橄榄油中的目标分析物依次通过正己烷和甲醇乙腈混合液(体积比1∶1)萃取后进样。结果表明:目标分析物含量在0.008～4mg/L范围内,线性度在0.993以上,相对标准偏差小于15%,方法检测限在0.0011～0.0052mg/L之间。A migration detection method for 9 bisphenol-type chemicals from food contacting materials was developed by using deionized water, 3 % （w/v） acetate acid solution, 10（v/v） ethanol solution and re- fined olive oil as four food simulants. The chemicals included bisphenol A, bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, and their derivatives. The analytes were separated in reverse phase liquid chromatographic column and detected by fluorescence detector. The water-based food simulants, including deionized water, 3 % （w/v） acetate acid solution and 10（v/v） ethanol solution, were directly sampled into HPLC, while the refined olive oil needs to be successively extracted by hexane and methanol/acetonitrile mixture （volume ratio= 1 ： 1） prior to sampling. It showed that the linearity is more than 0. 993 when concentrations of the analytes are between 0. 008 mg/L and 4 rag/L, the relative standard deviation is less than 15%, and the limits of detection are between 0. 0011 mg/L-0.0052 mg/L for the target analytes.

关 键 词：食品接触材料 双酚类物质 迁移 检测 

分 类 号：TB487[一般工业技术—包装工程] TS206.4[轻工技术与工程—食品科学]