Radical reduction of Passerini 3CR adducts by SmI_2/HMPA  

作　　者：Hui Yu Tao Gai Wen Liang Sun Mei Su Zhang 

机构地区：[1]Department of Chemistry,Tongji University,Shanghai 200092,China

出　　处：《Chinese Chemical Letters》2011年第4期379-381,共3页中国化学快报（英文版）

基　　金：NSFC for the financial support(No.20802053)

摘　　要：The Passerini 3-CR adducts of substituted cinnamaldehydes,isocyanides and acetic acid were treated with SmI2/HMPA in dry tetrahydrofuran（THF） at room temperature,andβ,γ-unsaturated amides were obtained in moderate yields.The reaction was supposed involving a radical reduction procedure.The Passerini 3-CR adducts of substituted cinnamaldehydes,isocyanides and acetic acid were treated with SmI2/HMPA in dry tetrahydrofuran（THF） at room temperature,andβ,γ-unsaturated amides were obtained in moderate yields.The reaction was supposed involving a radical reduction procedure.

关 键 词：Passerini ISOCYANIDE Modification AMIDES Samarium diiodide 

分 类 号：TQ131.12[化学工程—无机化工] O621.146[理学—有机化学]