ISOCYANIDE

作品数：28被引量：27H指数：3
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相关领域：理学更多>>
相关作者：李健杨晓鸣李健张欣邹晓民更多>>
相关机构：上海大学北京大学大连理工大学更多>>
相关期刊：《Chinese Journal of Polymer Science》《Chinese Journal of Structural Chemistry》《Science Bulletin》《International Journal of Organic Chemistry》更多>>
相关基金：国家自然科学基金广东省自然科学基金国家重点基础研究发展计划上海市青年科技启明星计划更多>>
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Oxidative cyclization of allyl compounds and isocyanide: A facile entry to polysubstituted 2-cyanopyrroles
《Chinese Chemical Letters》2024年第4期330-335,共6页Yaping Zhang Wei Zhou Mingchun Gao Tianqi Liu Bingxin Liu Chang-Hua Ding Bin Xu 
the National Natural Science Foundation of China(Nos.22171178, 21871174, 22071143);Innovation Program of Shanghai Municipal Education Commission (No.2019–01–07–00–09-E00008) for financial support。
A facile Tf OH-catalyzed oxidative cyclization of allyl compounds and isocyanide has been developed with the assistance of DDQ, where isocyanide is used as the crucial "N" and "CN" sources. Highly functionalized 2-cya...
关键词：ISOCYANIDE Cyanopyrrole INSERTION Allyl compound Bronsted acid catalysis 
Isocyanide-Based One-Pot Cascade Synthesis of 3-Acyl Isoindolinones
《Chinese Journal of Chemistry》2024年第3期259-263,共5页Jia Liu Yi-Ming Zhu Xiao-Ping Xu Shun-Jun Ji 
the National Natural Science Foundation of China(Nos.21772138 and 21672157);the Natural Science Foundation of Jiangsu Province(BK20221356);PAPD。
A series of 3-acyl-substituted isoindolinone derivatives were synthesized in a one-pot manner via the reaction of o-bromobenzaldehydes,isocyanides,and carboxylic acids in the presence of palladium catalyst and base. T...
关键词：One-pot reaction ISOCYANIDE Pd catalysis Rearrangement reaction ISOINDOLINONE 
Electrochemically promoted N-heterocyclic carbene polymercatalyzed cycloaddition of aldehyde with isocyanide acetate被引量：1
《Science China Chemistry》2022年第10期1873-1878,共6页Chu-Hong Ou Ying-Ming Pan Hai-Tao Tang 
supported by the Guangxi Natural Science Foundation of China (2021GXNSFFA220005);the Middle-Aged and Young Teachers’ Basic Scientific Research Ability Improvement Project of Guangxi (RZ1900005748);the Central Government Guides Local Science and Technology Development Fund Projects (guike ZY21195014);the National Natural Science Foundation of China (22061003,22161008)
N-heterocyclic carbene(NHC) is a potent organic small-molecule catalyst.However,its high synthetic price and frequent use in combination with excess oxidants have limited its utilization in industrial production.We de...
关键词：NHC catalysis ELECTROCHEMISTRY heterogeneous catalysis CYCLOADDITION 
A New Saddle-Shaped Aza Analog of Tetraphenylene: Atroposelective Synthesis and Application as a Chiral Acylating Reagent被引量：3
《CCS Chemistry》2022年第9期2897-2905,共9页Yu Luo Sidi Cheng Yan Peng Xilong Wang Jing Li Chunfang Gan Shuang Luo Qiang Zhu 
the National Natural Science Foundation of China(nos.21772198,21871268,and 22071250);the Frontier Research Program of Bioland Laboratory(Guangzhou Regenerative Medicine and Health Guangdong Laboratory)(no.2018GRZ110105017);the Natural Science Foundation of Guangdong Province of China(no.2020A1515011428);the“BAGUI Scholar”Program of Guangxi Province of China,and SKLRD Open Project(no.SKLRD-Z-202014)for financial support;the Guangzhou Branch of the Supercomputing Center of CAS for support.
(Z)-7-Aryl-5-acyldibenzo[e,g][1,4]diazocin-6(5H)-one,a unique saddle-shaped bridged biaryl containing synchronized aryl–aryl and N-aryl stereogenic axes,was constructed for the first time in good yields with up to 96...
关键词：diazocin tetraphenylene analog atroposelective synthesis double isocyanide insertion palladium catalysis 
Mononuclear aggregation-induced emission (AIE)-active gold(Ⅰ)-isocyanide phosphors: Contrasting phosphorescent mechanochromisms and effect of halogen substitutions on room-temperature phosphorescence nature
《Chinese Chemical Letters》2022年第5期2522-2526,共5页Xiaoyan Wang Zhao Chen Jun Yin Sheng Hua Liu 
support from the National Natural Science Foundation of China(Nos.22175069,22061018,21702079 and 21772054);the 111 Project(No.B17019),the Natural Science Foundation for Distinguished Young Scholars of Jiangxi Province(No.20212ACB213003);the Academic and Technical Leader Plan of Jiangxi Provincial Main Disciplines(No.20212BCJ23004).
Developing phosphors with long-lifetime(millisecond scale or even longer) solid state room temperature phosphorescence(RTP) feature has attracted considerable attention. However, to date, stimuli-responsive phosphors ...
关键词：Gold(I)complexes Halogen atoms Room temperature phosphorescence Aggregation-induced emission Phosphorescent mechanochromism 
Phosphinic Acid/Nal Mediated Reductive Cyclization Approach for Accessing the L-1-Deoxynojirimycin Using a Two-Component Three-Centered (2C3C) Ugi Type Reaction
《Chinese Journal of Chemistry》2021年第6期1503-1510,共8页Chandra S Azad Pratibha Shukla Mark A Olson Anudeep K Narula 
A catalytic two-component three-centered(2C3C)Ugi-type reaction was developed for the synthesis of L-1-deoxynojirimycin(DNJ)isomers using a chiron approach.This new and quite mild catalytic system,comprised of phenylp...
关键词：AZASUGARS Multicomponent reactions Nitrilium ion ISOCYANIDE Reductive cyclization 
Facile Mechanochemical Preparation of Polyamide-derivatives via Solid-state Benzoxazine-isocyanide Chemistry
《Chinese Journal of Polymer Science》2021年第5期573-584,I0006,共13页Xu Sun Wei Shi Xin-Yu Zhou Sheng Ding 
supported by the National Natural Science Foundation of China(No.21774103);the Youth Science and Technology Innovation Team of SWPU(Nos.2017CXTD05,2018CXTD05).
With the exploration of novel sustainable protocol for functional polyamides'(PAs)construction as the starting point,herein,the small molecular model compound(M 1-ssBIC)was prepared firstly by manual grinding of monof...
关键词：MECHANOCHEMISTRY Solid-state synthesis BENZOXAZINE ISOCYANIDE POLYAMIDE 
The First-principles Study on the Rectification of Molecular Junctions Based on the Alkyl-chain-modified[2,5?]Bipyrimidinyl(biphenyl isocyanide)gold(Ⅰ)被引量：1
《Chinese Journal of Structural Chemistry》2020年第10期1763-1769,1741,共8页GAO Quan-Dang YANG E 
the National Natural Science Foundation of China(21401023)。
Using density functional theory(DFT)combined with nonequilibrium Green?s function investigates the electron-transport properties of several molecular junctions based on the[2,5?]bipyrimidinyl(biphenyl isocyanide)gold(...
关键词：the first-principles isocyanide gold(Ⅰ)compound alkyl chain rectifying ratio 
Catalyst-free formal[4+1]/[4+2]cyclization cascade sequence of isocyanides with two molecules of acylketene formed in situ from thermal-induced Wolff rearrangement of 2-diazo-1,3-diketones
《Science Bulletin》2020年第8期670-677,M0004,共9页Jian Luo Guo-Shu Chen Shu-Jie Chen Yun-Lin Liu 
supported by the National Natural Science Foundation of China(21801050);the Scientific Research Project of Guangzhou Municipal Colleges and Universities(201831816)。
An expedient and economic approach for constructing O,O,N-spiro compounds consisting of both a 1,3-oxazine and a furan ring through a catalyst-free formal[4+1]/[4+2]cycloaddition cascade sequence of isocyanides with t...
关键词：CATALYST-FREE ISOCYANIDE Acylketene 2-Diazo-1 3-diketone Wolff rearrangement 
Mn(Ⅲ)-mediated radical cascade reaction of boronic acids with isocyanides:Synthesis of diimide derivatives
《Chinese Chemical Letters》2019年第2期379-382,共4页Fei Wang Tian-Qi Wei Pei Xu Shun-Yi Wang Shun-Jun Ji 
the National Natural Science Foundation of China(Nos. 21772137, 21672157, 21372174);the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (No. 16KJA150002);the Ph.D. Programs Foundation of PAPD;the project of scientific and technologic infrastructure of Suzhou (No. SZS201708);Soochow University for financial support
A manganese (Ⅲ)-promoted oxidative radical cascade reaction of easily accessible arylboronic acids with isocyanides to construct diimide derivatives was studied. This protocol provides a new way to synthesis of acety...
关键词：Mn(OAc)3 ISOCYANIDE Arylboronic acid DIIMIDE DERIVATIVES RADICAL CASCADE 
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