Studies on Diastereoselective Intramolecular meta-Cycloaddition ofArene to Olefin (Part I)  

作　　者：Shen, XM Guo, XC Sun, LD Zhang, C 

机构地区：[1]Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China

出　　处：《Chinese Chemical Letters》1998年第2期131-134,共4页中国化学快报（英文版）

摘　　要：The photoinduced intramolecular meta-cycloaddition of bichromophores 1a-1d gave diastereoselectively two types of adducts, 2a-2d and 3a-3d. respectively. The observed stereochemistry of cycloaddition was rationalized in terms of hydrogen bond effect induced by the 3-hydroxy group in the 5-phenylpent-1-ene skeleton.The photoinduced intramolecular meta-cycloaddition of bichromophores 1a-1d gave diastereoselectively two types of adducts, 2a-2d and 3a-3d. respectively. The observed stereochemistry of cycloaddition was rationalized in terms of hydrogen bond effect induced by the 3-hydroxy group in the 5-phenylpent-1-ene skeleton.

关 键 词：ARENE OLEFIN meta-cycloaddition DIASTEREOSELECTIVITY 

分 类 号：O621[理学—有机化学]