卤代甲烷分子中s键轨道的特征  

THE CHARACTER OF s-HYBRID BONDING ORBITALS IN THE HALOMETHANES

作　　者：胡振明[1] 林险峰[2] 

机构地区：[1]湖北师范学院 [2]四平师范学院

出　　处：《吉林师范大学学报（自然科学版）》1991年第3期11-15,共5页Journal of Jilin Normal University:Natural Science Edition

摘　　要：本文借助最大重叠杂化轨道理论,研究了卤代甲烷系列分子的红外伸缩频率,基团电负性和质子酸度等分子性质与结构的关系.明确地反映了这类分子的化学键特征和卤素取代基对分子性质的影响.The maximum overlap method was used to study the relationships the C-H stretching frequencies, group electronegativities and proton acidity properties and the molecular structure in the halomethanes. The results gives a good description of the effect of the character of bond and the effect of halogen-substitvted on the properties.

关 键 词：最大重叠法 杂化轨道 s轨道成分 电负性 

分 类 号：N[自然科学总论]