气相色谱-质谱法测定白酒中16种邻苯二甲酸酯  

Determination of 16 Phthalic Acid Esters in Spirit by Gas Chromatography/Mass Spectrometry

作　　者：方志青[1] 林野 王娅[1] 张颂富[1] 曹可名[1] 

机构地区：[1]贵州民族大学化学与环境科学学院,贵州贵阳550025 [2]贵州省疾病预防控制研究中心,贵州贵阳550001

出　　处：《食品与生物技术学报》2015年第1期108-111,共4页Journal of Food Science and Biotechnology

基　　金：贵州省科学技术基金项目(JLKM201202)

摘　　要：为检测白酒中16种邻苯二甲酸酯类化合物（PAEs）的残留量,建立了液液萃取-气相色谱-质谱法测定白酒中16种邻苯二甲酸酯类化合物。样品采用沸水浴加热先除去乙醇后再用正己烷提取测定,在0.5~8.0mg/L范围内线性关系良好,相关系数均大于0.997,检出限为0.02~0.05mg/L,样品加标回收率为82%~106%,结果表明：该方法操作简便、分析快速,能够满足于白酒中16种PAEs的检测分析要求。To determine the residual amounts of 16 Phthalic Acid in spirit,a liquid-liquid extraction combined with gas chromatography/mass spectrometry was established. The results showed that linearity of response over 16 phthalic acid esters was good from 0.5 to 8.0mg/L with higher correlation coefficients（0.997）.The limits of detection were from 0.02 to 0.05mg/L,in addition,the relative standard deviations（RSDs） were in the range of 0.7%-2.8%. Spike recoveries ranged from 82% to 106% for all samples in same analysis condition. The conclusion indicated that this developed method is simple and quick response for the determination of 16 Phthalic Acid Esters in wine.

关 键 词：气质联用 白酒 邻苯二甲酸酯类 测定 

分 类 号：X836[环境科学与工程—环境工程] O657.63[理学—分析化学]