结合科研课题进行有机化学教学——以红荧烯衍生物的合成为例  

Combining Research Projects for Organic Chemistry Teaching:Taking the Synthesis of Rubrene Derivatives as an Example

作　　者：刘涛[1] 夏宏宇[1] 杜荣斌[1] 孔学军[1] 徐衡[1] 

机构地区：[1]安庆师范学院化学化工学院,安徽安庆246011

出　　处：《安庆师范学院学报（自然科学版）》2015年第1期127-130,共4页Journal of Anqing Teachers College(Natural Science Edition)

基　　金：安徽省教学研究项目(2014jyxm238;2013jyxm149)

摘　　要：红荧烯衍生物是一种新型功能性荧光材料,有着潜在的应用前景。以对苯醌为原料,经九步反应合成了红荧烯衍生物,其中涉及Diels-Alder反应、氧化、脱水、卤代、水解、亲核加成及缩合反应等。在教学中结合荧烯衍生物合成的实例,渗透到相关反应,拓宽了学生的视野,激发了学生对有机合成的兴趣,有较好的教学效果。Rubrene derivatives are a kind of novel functional fluorescent materials,and have potential applications. P-benzoquinone as raw material,by nine- step reaction,rubrene derivatives were synthesized,which involves the Diels- Alder reaction,oxidation,dehydration,halogenation,hydrolysis,nucleophilic addition and condensation reactions,and so on. In organic chemistry teaching,combining with the examples of rubrene derivatives synthesis,penetration into related reactions broadened the students＇ vision,stimulated students＇ interest in organic synthesis and achieved better teaching effect.

关 键 词：红荧烯衍生物 有机化学 教学实践 

分 类 号：G642[文化科学—高等教育学]