高度分散的Fe_2O_3/SiO_2的合成及对F-T反应的催化性能  

Preparation and Fischer-Tropsch Catalytic Activity of High Dispersed Fe_2O_3/SiO_2 Catalyst

作　　者：曹崇江[1,2] 陈晓蓉[3] 宋伟[1] 鞠兴荣[1] 

机构地区：[1]南京财经大学食品科学与工程学院应用化学系,南京210023 [2]伊利诺伊州大学化学工程系,美国芝加哥60607 [3]南京工业大学化学与化工学院,南京210009

出　　处：《化学通报》2014年第12期1208-1213,共6页Chemistry

基　　金：国家科技部支持计划项目(2013BAD17B01);江苏省高校自然科学基金项目(13KJD550002)资助

摘　　要：以初湿浸渍法为基础,柠檬酸为分散剂,制备出Fe2O3在SiO2载体上高度分散的F-T催化剂,通过N2吸脱附技术、X射线衍射、扫描透射电镜和程序升温还原对催化剂的结构,形貌及组成进行表征,结果表明,在柠檬酸分散作用下,浸渍过程中Fe离子与SiO2载体之间的静电吸附作用使Fe离子稳定、均匀地分散于SiO2表面,在烘干、焙烧过程中未发生团聚现象,形成高度分散、均匀的纳米颗粒,粒径平均尺寸为1.1nm。以F-T合成反应作为模型反应对催化活性进行表征,该法合成的催化剂表现出较优异的稳定性,反应500h后CO转化率保持在35.1%。An efficient method to synthesize highly dispersed Fe2O3/ SiO2 catalysts for Fischer-Tropsch reaction was described. The synthesis of well-dispersed Fe2O3/ SiO2 was carried out via incipient wetness method in the presence of citric acid. The resulting samples were characterized by using N2adsorption-desorption techniques,XRD,STEM,and TPR. The results showed that iron oxide was well-dispersed over the SiO2 support in the presence of citric acid. Owing to the electrostatic adsorption interactions between the iron species and the SiO2 support,sintering and agglomeration were inhibited during the preparation process so that high dispersed Fe2O3 particles were obtained after drying and calcination. The particles size of the deposited Fe2O3 was uniform and the average size is 1. 1nm. In the F-T reaction,the catalyst showed higher F-T activity and stability. The CO conversion reached 35. 1% after 500 h reaction.

关 键 词：催化剂 F-T合成 氧化铁 氧化硅 

分 类 号：O643.36[理学—物理化学]