Synthesis of Substituted Benzoxacycles via a Pd（ll）-Catalyzed Intramolecular Arylation Reaction of Allylic Alcohols  

作　　者：Jingjie Li Ceheng Tan Xinpeng Mu Jianxian Gong Zhen Yang 

机构地区：[1]Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen, Guangdong 518055, China [2]Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education and Beijing National Laboratory for Molecular Science (BNLMS) and Peking-Tsinghua Center for Life Sciences, Peking University, Beijing 100871, China

出　　处：《Chinese Journal of Chemistry》2017年第5期562-566,共5页中国化学（英文版）

摘　　要：ein a Pd-catalyzed intramolecular allylation reaction of unprotected allylic alcohols was developed,and the reaction proceeded through a Pd（Ⅱ）-mediated allylic carbocation species formation,followed by a Friedel-Crafts type annulation to afford functionalized chromanes.ein a Pd-catalyzed intramolecular allylation reaction of unprotected allylic alcohols was developed,and the reaction proceeded through a Pd（Ⅱ）-mediated allylic carbocation species formation,followed by a Friedel-Crafts type annulation to afford functionalized chromanes.

关 键 词：PD-CATALYZED Friedel-Crafts reaction benzoxacycles ARYLATION allylic compound 

分 类 号：O[理学]