相关期刊:《Chinese Journal of Chemical Physics》《Natural Products and Bioprospecting》《Science China Chemistry》《Chemical Research in Chinese Universities》更多>>
An efficient and novel approach is proposed for oxidative arylation of bio-based furfuryl alcohol(FA)to aryl furans(AFs),a versatile monomer of photoelectric materials,in the presence of UiO-67-Pd(F)with phenanthrolin...
financial support of National Natural Science Foundation of China(21901193,22271314 and 22377097);the innovation foundation of Key Laboratory of Green Chemical Engineering Process of Ministry of Education(GCX2023002).
Concise assembly of spirooxindoles is of great significance but a challenging task in modern organic synthesis.Described herein is an unusual base-promoted[4+2]spiroannulation of rarely used isatin-derivedβ-silylcarb...
supported by the National Natural Science Foundation of China(22271062);Doctoral Scientific Research Foundation of Gannan Normal University(BSJJ202303).
We herein describe a Cp^(*)Rh^(Ⅲ)-catalyzed C(sp^(3))–H mono-arylation of 8-methylquinolines with benign arylsilanes.The use of 1-adamantane carboxylic acid can benefit the efficiency in this transformation,and AgF ...
Considering the widespread presence of the dithiocarbamate skeleton in pharmaceuticals and bioactive molecules,the development of novel and convenient methods for the synthesis of these useful sulfur-containing compou...
supported by the National Natural Science Foundation of China(Nos.21901185 and 22301216);funds provided by Tianjin Normal University。
Herein,we report the migratory hydroarylation of unactivated alkenes with aryl iodides using native and weakly coordinating amide directors under mild conditions.Synergistic coordination of the monodentate directing g...
support from the University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province(No.UNPYSCT-2017124)。
We report the unprecedent Pd(I)catalyzed ring-opening arylation of cyclopropyl-α-aminoamides.This protocol allows facile access to biologically important α-ketoamide-containing oligopeptides and even more challengin...
supported by the National Key R&D Program of China(2021YFA1500100);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0610000);the National Natural Science Foundation of China(21821002,22361142834,and 22101294);the S&TCSM of Shanghai(21ZR1476500);Natural Science Foundation of Ningbo(2023J035)。
The merging of transition metal catalysis with electrochemistry has become a powerful tool for organic synthesis because catalysts can govern the reactivity and selectivity.However,coupling catalysts with alkyl radica...
the funding support of the National Key R&D Program of China(2021YFF0701600);NSFC(21901043,21921003,and 22031004);STCSM(21ZR1445900)and Shanghai Municipal Education Commission(20212308).
Comprehensive Summary,Herein,we report nickel-catalyzed cross-coupling of gem-difluorinated cyclopropanes with boronic acids,providing the corresponding arylated 2-fluoroallylic scaffolds.This approach used commercial...
supported by the National Natural Science Foundation of China(22001065);the Science and Technology Foundation of Hunan Province(2021JJ30090);Guangdong Provincial Key Laboratory of Catalysis(2020B121201002);Shenzhen Science and Technology Program(KQTD20210811090112004);supported by Center for Computational Science and Engineering at SUSTech;the CHEM high-performance supercomputer cluster(CHEM-HPC)located at the Department of Chemistry,SUSTech。
The conversion of commercially available chiral sulfinamides into pharmaceutically useful chiral sulfoximines via direct SIVfunctionalization is synthetically attractive but challenging due to the competitive reaction...
supported by the National Key Research and Development Program of China(No.2018YFA0704502);the National Natural Science Foundation of China(Nos.21871261,21931011);Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZZ105).
Native amino-directed palladium-catalyzed C(sp^(3))-H activation/functionalization has been developed for modification ofα-amino acids and peptides.Herein a palladium(Ⅱ)-catalyzed C(sp^(2))-H arylation ofα-amino-β...