ARYLATION

作品数:76被引量:40H指数:3
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相关领域:理学更多>>
相关作者:王刚伟陆丽丽陈文新邵黎雄惠新平更多>>
相关机构:温州大学兰州大学中国人民大学浙江师范大学更多>>
相关期刊:《Chinese Journal of Chemical Physics》《Natural Products and Bioprospecting》《Science China Chemistry》《Chemical Research in Chinese Universities》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划天津市自然科学基金山东省自然科学基金更多>>
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Switching electronic effects of UiO-67-Pd using fluorinated ligands for catalytic oxidative arylation of bio-based furfuryl alcohol
《Chinese Journal of Catalysis》2025年第2期230-240,共11页Dongwen Guo Guohui Zeng Jinxing Long Biaolin Yin 
国家自然科学基金(22178129);广东省自然科学基金(2023A1515010771)。
An efficient and novel approach is proposed for oxidative arylation of bio-based furfuryl alcohol(FA)to aryl furans(AFs),a versatile monomer of photoelectric materials,in the presence of UiO-67-Pd(F)with phenanthrolin...
关键词:Bio-based furan Catalytic oxidative arylation UiO-67-Pd(F)catalyst Ligand regulation Charge separation 
Modular Assembly of Six-Membered Carbocyclic Spirooxindoles via Peterson Olefination/Michael Addition/C(sp^(3))Arylation Cascade
《Chinese Journal of Chemistry》2024年第21期2614-2620,共7页Feng-Cheng Jia Zi-Yi Yuan Na Luo Shuang-Xi Gu Xiao-Qiang Hu 
financial support of National Natural Science Foundation of China(21901193,22271314 and 22377097);the innovation foundation of Key Laboratory of Green Chemical Engineering Process of Ministry of Education(GCX2023002).
Concise assembly of spirooxindoles is of great significance but a challenging task in modern organic synthesis.Described herein is an unusual base-promoted[4+2]spiroannulation of rarely used isatin-derivedβ-silylcarb...
关键词:Cascade reaction SPIROOXINDOLE Peterson olefination C(sp^(3))arylation of oxindole Transition-metal-free 
Rhodium-Catalyzed C(sp^(3))–H Arylation of 8-Methylquinolines with Arylsilanes
《Chinese Journal of Chemistry》2024年第21期2627-2632,共6页Lin Li Haidong Liu Yupeng Qian Guohong Shen Yun Shi Jiajie Du Haiqing Luo 
supported by the National Natural Science Foundation of China(22271062);Doctoral Scientific Research Foundation of Gannan Normal University(BSJJ202303).
We herein describe a Cp^(*)Rh^(Ⅲ)-catalyzed C(sp^(3))–H mono-arylation of 8-methylquinolines with benign arylsilanes.The use of 1-adamantane carboxylic acid can benefit the efficiency in this transformation,and AgF ...
关键词:C(sp^(3))-H arylation C-H activation ARYLSILANES CROSS-COUPLING Nitrogen heterocycles 
Electron donor-acceptor complex enabled arylation of dithiocarbamate anions with thianthrenium salts under aqueous micellar conditions
《Chinese Chemical Letters》2024年第11期1-2,共2页Rong-Nan Yi Wei-Min He 
Considering the widespread presence of the dithiocarbamate skeleton in pharmaceuticals and bioactive molecules,the development of novel and convenient methods for the synthesis of these useful sulfur-containing compou...
关键词:ALKYL donor SALTS 
Highly selectiveα-C(sp^(3))-H arylation of alkenyl amides via nickel chain-walking catalysis
《Chinese Chemical Letters》2024年第7期271-275,共5页Haoran Shi Jiaxin Wang Yuqin Zhu Hongyang Li Guodong Ju Lanlan Zhang Chao Wang 
supported by the National Natural Science Foundation of China(Nos.21901185 and 22301216);funds provided by Tianjin Normal University。
Herein,we report the migratory hydroarylation of unactivated alkenes with aryl iodides using native and weakly coordinating amide directors under mild conditions.Synergistic coordination of the monodentate directing g...
关键词:Alkenes HYDROARYLATION Chain-walking Regioselective Nickel catalysis 
Pd(I)-catalyzed ring-opening arylation of cyclopropyl-α-aminoamides:Access toα-ketoamide peptidomimetics
《Chinese Chemical Letters》2024年第6期320-326,共7页Yue Sun Liming Yang Yaohang Cheng Guanghui An Guangming Li 
support from the University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province(No.UNPYSCT-2017124)。
We report the unprecedent Pd(I)catalyzed ring-opening arylation of cyclopropyl-α-aminoamides.This protocol allows facile access to biologically important α-ketoamide-containing oligopeptides and even more challengin...
关键词:Pd(I)catalysis Ring-opening arylation Domino reactions Oligopeptides Late-stage functionalization 
基于成对电解和光催化协同作用的镍催化环烷醇的芳基化反应
《Science Bulletin》2024年第12期1866-1874,共9页刘昭然 朱萧谕 郭剑峰 马聪 左智伟 梅天胜 
supported by the National Key R&D Program of China(2021YFA1500100);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0610000);the National Natural Science Foundation of China(21821002,22361142834,and 22101294);the S&TCSM of Shanghai(21ZR1476500);Natural Science Foundation of Ningbo(2023J035)。
The merging of transition metal catalysis with electrochemistry has become a powerful tool for organic synthesis because catalysts can govern the reactivity and selectivity.However,coupling catalysts with alkyl radica...
关键词:Organic electrochemistry Electrophotocatalysis Paired electrolysis Ni catalysis Remote arylation 
Nickel-Catalyzed Regio-and Stereoselective Defluorinative Arylation of gem-Difluorinated Cyclopropanes
《Chinese Journal of Chemistry》2024年第8期823-828,共6页Shutao Qi Yunkai Hua Liangkai Pan Junfeng Yang Junliang Zhang 
the funding support of the National Key R&D Program of China(2021YFF0701600);NSFC(21901043,21921003,and 22031004);STCSM(21ZR1445900)and Shanghai Municipal Education Commission(20212308).
Comprehensive Summary,Herein,we report nickel-catalyzed cross-coupling of gem-difluorinated cyclopropanes with boronic acids,providing the corresponding arylated 2-fluoroallylic scaffolds.This approach used commercial...
关键词:Nickel Monofluoroolefin CYCLOPROPANE Regioselectivity STEREOSELECTIVITY C-C coupling Cross-coupling Synthetic methods 
Strain-promoted S-arylation and alkenylation of sulfinamides using arynes and cyclic alkynes
《Science China Chemistry》2024年第3期928-935,共8页Xi Zou Boming Shen Gao-lin Li Qian Liang Yanhua Ouyang Binghe Yang Peiyuan Yu Bing Gao 
supported by the National Natural Science Foundation of China(22001065);the Science and Technology Foundation of Hunan Province(2021JJ30090);Guangdong Provincial Key Laboratory of Catalysis(2020B121201002);Shenzhen Science and Technology Program(KQTD20210811090112004);supported by Center for Computational Science and Engineering at SUSTech;the CHEM high-performance supercomputer cluster(CHEM-HPC)located at the Department of Chemistry,SUSTech。
The conversion of commercially available chiral sulfinamides into pharmaceutically useful chiral sulfoximines via direct SIVfunctionalization is synthetically attractive but challenging due to the competitive reaction...
关键词:ARYLATION ALKENYLATION SULFOXIMINES sulfinamides ARYNES 
Free amino group-directed C(sp^(2))-H arylation ofα-amino-β-aryl esters by palladium catalysis
《Chinese Chemical Letters》2024年第2期358-360,共3页Yue Gao Yu Du Weiping Su 
supported by the National Key Research and Development Program of China(No.2018YFA0704502);the National Natural Science Foundation of China(Nos.21871261,21931011);Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZZ105).
Native amino-directed palladium-catalyzed C(sp^(3))-H activation/functionalization has been developed for modification ofα-amino acids and peptides.Herein a palladium(Ⅱ)-catalyzed C(sp^(2))-H arylation ofα-amino-β...
关键词:Native amino-directed Palladium catalyst C(sp^(2))-H arylation α-Amino-β-aryl ester Chiralα-amino acid 
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