supported by the National Natural Science Foundation of China(22001065);the Science and Technology Foundation of Hunan Province(2021JJ30090);Guangdong Provincial Key Laboratory of Catalysis(2020B121201002);Shenzhen Science and Technology Program(KQTD20210811090112004);supported by Center for Computational Science and Engineering at SUSTech;the CHEM high-performance supercomputer cluster(CHEM-HPC)located at the Department of Chemistry,SUSTech。
The conversion of commercially available chiral sulfinamides into pharmaceutically useful chiral sulfoximines via direct SIVfunctionalization is synthetically attractive but challenging due to the competitive reaction...
the National Natural Science Foundation of China(No.21961015);the Natural Science Foundation of Jiangxi Province(No.20202ACBL203005)for their financial support.
Disclosed herein is a novel Rh/Ag co-catalyzed S=NH directed C–H activation and C–H/N–H bond functionalization protocol of free NH-sulfoximines with hypervalent iodonium ylides.With the aid of AgOTf,these C–H func...
supported by the National Natural Science Foundation of China(21372034);the State Key Laboratory of Geohazard Prevention and Geoenvironment Protection(SKLGP2018Z002)
The visible light-promoted synthesis of N-aroylsulfoximines has been accomplished via an oxidative dehydrogenative coupling at room temperature under air without the addition of a photosensitizer, metal catalyst, or b...
This work was supported by the National Natural Science Foundation of China (31370039, 21772103 and 21602118) and the Tianjin Natural Science Foundation (16JCYBJC29400 and 17JCYBJC19900).
The sulfoximine group has been evaluated as a pharmacophore. Introducing the sulfoximine structure into medicinal compounds as exciting motifs has brought opportunities in drug discovery. In order to develop new ryano...
This work was supported by Syngenta Postgraduate Fellowship,National Basic Research Program of China(No.2010CB126106);the National Key Technologies R&D Program(No.2011BAE06B05).
Due to a novel mode action,low toxicity to mammals and low residue characteristics,phthalic acid diamides have aroused considerable interests in agricultural chemistry.With introduction of N-cyano,N-trifluoroacetyl,N-...
The regiochemistry of 1,3-dipolar cycloaddition reactions of C,N-diphenyl nitrone with some vinyl sulfoximines as dipolarophile was investigated using density functional theory (DFT)-based reactivity indexes and act...