ARYNES

作品数：7被引量：3H指数：1
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相关领域：理学更多>>
相关作者：任智卉关正辉王尧宇更多>>
相关机构：中国科学技术大学北京化工大学西北大学更多>>
相关期刊：《Chinese Journal of Chemistry》《Science China Chemistry》《Chinese Chemical Letters》《Organic Chemistry Frontiers》更多>>
相关基金：国家自然科学基金更多>>
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Strain-promoted S-arylation and alkenylation of sulfinamides using arynes and cyclic alkynes
《Science China Chemistry》2024年第3期928-935,共8页Xi Zou Boming Shen Gao-lin Li Qian Liang Yanhua Ouyang Binghe Yang Peiyuan Yu Bing Gao 
supported by the National Natural Science Foundation of China(22001065);the Science and Technology Foundation of Hunan Province(2021JJ30090);Guangdong Provincial Key Laboratory of Catalysis(2020B121201002);Shenzhen Science and Technology Program(KQTD20210811090112004);supported by Center for Computational Science and Engineering at SUSTech;the CHEM high-performance supercomputer cluster(CHEM-HPC)located at the Department of Chemistry,SUSTech。
The conversion of commercially available chiral sulfinamides into pharmaceutically useful chiral sulfoximines via direct SIVfunctionalization is synthetically attractive but challenging due to the competitive reaction...
关键词：ARYLATION ALKENYLATION SULFOXIMINES sulfinamides ARYNES 
Ultralong Organic Phosphorescence Modulation of Aromatic Carbonyls and Multi-Component Systems
《Chinese Journal of Chemistry》2022年第16期1987-2000,共14页Chunguang Ren Zhengshuo Wang Tianjie Wang Jiayi Guo Yifeng Dai Hua Yuan Yeqiang Tan 
financially supported by the Shandong Provincial Natural Science Foundation(Nos.ZR2021JQ16,ZR2019YQ19and ZR2019BEM018);the Project of Shandong Province Higher Educational Science and Technology Program(No.2019KJA026);the National Natural Science Foundation of China(Nos.51403113 and 52072193);the Shandong Provincial College Students'Innovative Entrepreneurial Training(No.S202111065214).
Aromatic carbonyls have evoked sustained attention in the field of room-temperature phosphorescence(RTP).The introduction of carbonyl groups is a general way to achieve RTP for their effective intersystem crossing(ISC...
关键词：ARYNES Carbonyl ligands Ultralong organic phosphorescence Molecular design Processing strategy 
Transition-metal-free synthesis of 4-aminoisoquinolin-1(2H)-ones via a tandem reactionof arynes and oxazoles
《Organic Chemistry Frontiers》2022年第6期1550-1555,共6页Shaojun Liu Pei Xie Leifang Wu Jixing Zhao Zhihua Cai Lin He 
supported by the National Natural Science Foundation of China(No.22161039);the Excellent Young Teachers Plan of Bingtuan(2017CB001 and CZ027203,CZ002203);the International Cooperation Project of Shihezi University(No.GJHZ201801).
A facile and transition-metal-free method for the synthesis of 4-amino isoquinolin-1(2H)-ones has beendeveloped. Arynes react with 4,5-disubstituted oxazoles through a tandem Diels–Alder reaction/dehydrogenation–aro...
关键词：synthesis TRANSITION 
Synthesis of π-extended dibenzo[d,k]ullazines by a palladium-catalyzed double annulation using arynes被引量：1
《Chinese Chemical Letters》2021年第4期1407-1410,共4页Deping Wang Yan Liu Linhua Wang Hu Cheng Yuming Zhang Ge Gao 
the financial support from the National Natural Science Foundation of China(No.21772134);the Fundamental Research Funds for the Central Universities(No.20826041D4117)。
An efficient Pd-catalyzed double annulation reaction of 1-(2,6-dibro mophenyl)-1 H-pyrroles with arynes is developed to synthesizeπ-extended dibenzo[d,k]ullazines in good to excellent yields.For the first time,the pa...
关键词：Ullazine Dibenzo[d k]ullazine Palladium catalysis ANNULATION ARYNE 
Fused multifunctionalized bridge aromatic hydrocarbons from in situ-generated arynes and anthracene derivatives
《Chinese Chemical Letters》2020年第5期1305-1308,共4页Baohua Liu Qiong Hu Feihu Yang Xiaojie Zheng Yimin Hu 
the National Natural Science Foundation of China(Nos.21572002,21272005);The Research Culture Funds of Anhui Normal University;Department of Human Resources of Anhui Province for financial support。
This study presents a facile strategy for the formation of highly substituted butterfly 1,4-adducts/9,10-adducts via the Diels-Alder reaction of benzyne intermediates.The method achieves very good to excellent yields ...
关键词：Bridge aromatics HDDA reaction BENZYNES Anthracene 
Highly efficient synthesis of 9-aminoxanthenes via the tandem reaction of arynes with salicyl N-tosylimines被引量：2
《Chinese Chemical Letters》2012年第12期1359-1362,共4页Lin He Ji Xin Pian Jing Zhang Yuan Zhen Li 
the National Natural Science Foundation of China(No.21162022);the Team Innovation Project of Shihezi University(No.2011ZRKETD-04) for financial support
A cascade insertion-nucleophilic annulation reaction of salicyl N-tosylimines with aryne generated in situ from 2-（trimethyl- silyl） aryl triflate and KF-18-crown-6 has been developed, providing 9-aminoxanthenes eff...
关键词：Salicyl N-tosylimines ARYNE 9-Aro.inoxanthene 
The facile insertion of β-keto sulfones to arynes:The direct preparation of polysubstituted ortho-keto benzyl sulfones
《Chinese Chemical Letters》2008年第6期631-633,共3页Jian Xue Lu Ling Wu Xian Huang 
We are grateful to the National Natural Science Foundation of China （Nos. 20332060 and 2472072）
One novel carbon-carbon bond insertion reaction of arynes has been developed. By this reaction β-keto sulfones can insert the triple bond of arynes to prepare polysubstituted ortho-keto benzyl sulfones.
关键词：ARYNES Insertion reaction C-C bonds β-Keto sulfones 
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