Chiral organobases: Properties and applications in asymmetric catalysis  

作　　者：Weidi Cao Xiaohua Liu Xiaoming Feng 

机构地区：[1]Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University

出　　处：《Chinese Chemical Letters》2018年第8期1201-1208,共8页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China (Nos. 21625205 and 21332003);the National Program for Support of Top-Notch Young Professionals for financial support

摘　　要：Chiral organobases occupy a significant position in asymmetric organocatalysis. The general types of chiral organobases include tertiary amines, amidines, guanidines, cyclopropenimines, and iminophosphoranes, etc. These organobases are demonstrated to be effective organocatalysts to promote divers kinds of base-initiated reactions in excellent yields and stereoselectivities. In previous reports, several groups have summarized each kind of chiral organobases in different reviews. To the aim of understanding the whole of them in one review, herein, we provide a brief introduction of these chiral organobases in asymmetric catalysis.Chiral organobases occupy a significant position in asymmetric organocatalysis. The general types of chiral organobases include tertiary amines, amidines, guanidines, cyclopropenimines, and iminophosphoranes, etc. These organobases are demonstrated to be effective organocatalysts to promote divers kinds of base-initiated reactions in excellent yields and stereoselectivities. In previous reports, several groups have summarized each kind of chiral organobases in different reviews. To the aim of understanding the whole of them in one review, herein, we provide a brief introduction of these chiral organobases in asymmetric catalysis.

关 键 词：Chiral organobases Asymmetric organocatalysis AMINES AMIDINES GUANIDINES Cyclopropenimines Iminophosphoranes 

分 类 号：O621.251[理学—有机化学]