碳硼烷化学发展之路  

Development of Carborane Chemistry

作　　者：赵薇佳 贺嘉俊 芦昌盛[1,2] ZHAO Weijia;HE Jiajun;LU Changsheng(School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,P.R.China;National Demonstration Center for Experimental Chemistry Education,Nanjing University,Nanjing 210023,P.R.China)

机构地区：[1]南京大学化学化工学院,南京210023 [2]南京大学国家级化学实验教学示范中心,南京210023

出　　处：《大学化学》2019年第1期39-47,共9页University Chemistry

摘　　要：碳硼烷分子具有独特的笼状结构,能够表现出三维芳香性和稳定的物理化学性质,这使得碳硼烷不仅能够应用于有机硼化学及金属有机化学,而且在生物学、材料学等领域也有不错的应用前景。本文叙述了碳硼烷化学的发展历史、碳硼烷化合物的结构性质,并简要介绍了碳硼烷近年来在生物医学、发光材料以及催化剂领域的应用,希望对读者了解碳硼烷化学的新进展能够有所帮助。Carboranes exhibit three-dimensional aromaticity as well as stable physical and chemical properties due to their unique molecular cages,which not only enable the wide application in organoboron and organometallic chemistry,but also result in increasing potential applications in fields such as biology and materials science.This article briefly describes the development of carborane chemistry and the structural properties of carboranes,in particular reviewing recent progresses of carboranes in biomedicine,luminescent material,and catalysis.The authors hope to give a hand to readers in a quick scan of the most recent progresses in carborane chemistry.

关 键 词：碳硼烷 生物成像 BNCT药物 发光材料 

分 类 号：G64[文化科学—高等教育学] O613.81[文化科学—教育学]