Palladium-Catalyzed Three-Component Coupling Reaction of Allyl Carboxylates, Norbornenes and Diboronates InvoIving Sequential Olefins Insertion and Borylation Reaction  

作　　者：Zun Li Jia Zheng Chunsheng Li Wanqing Wu Huanfeng Jiang 

机构地区：[1]Key Laboratory of Functional Molecular Engineering of Guangdong Province,School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou,Guangdong 510640,China

出　　处：《Chinese Journal of Chemistry》2019年第2期140-147,共8页中国化学（英文版）

基　　金：the National Program on Key Research Project (No. 2016YFA0602900);the National Natural Science Foundation of China (No. 21420102003);the Guangdong Province Science Foundation (No. 2017B090903003) for financial support.

摘　　要：Summary of main observation and conclusion An efficient Pd-catalyzed three-component coupling reaction of allyl carboxylates, norbornenes and diboronates is described, which allows efficient assembly of C(sp3)-C(sp3) and C(sp3)-B bonds in a single process. Moreover, this approach shows advantages of good chemo- and regioselectivity, as well as good substrates suitability.

关 键 词：PALLADIUM-CATALYZED THREE-COMPONENT Coupling REACTION ALLYL CARBOXYLATES 

分 类 号：O6[理学—化学]