ALLYL

作品数：109被引量：140H指数：7
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Gold-catalyzed intermolecular amination of allyl azides with ynamides:Efficient construction of 3-azabicyclo[3.1.0]scaffold
《Chinese Chemical Letters》2025年第2期356-360,共5页Chong-Yang Shi Jian-Xing Gong Zhen Li Chao Shu Long-Wu Ye Qing Sun Bo Zhou Xin-Qi Zhu 
financial support from the National Natural Science Foundation of China(Nos.22125108,22331004 and 22121001);Yunnan Normal University,Applied Basic Research Projects of Yunnan Province(No.202101AT070217);the Jiangxi Provincial Natural Science Foundation(No.20224BAB213013);the Jiangxi Provincial Department of Education in Science and Technology Program Project(No.GJJ210906)。
Gold-catalyzed amination reactions based on azides viaα-imino gold carbene intermediates have attracted extensive attention in the past decades because this methodology leads to the facile and efficient construction ...
关键词：GOLD AZIDES Alkynes AMINATION HETEROCYCLES 
Palladium-Catalyzed Selective Syntheses of 2,3-Allenyl Amines via Double Functionalization Coupling of 2-Alkynyl-1,4-diol Dicarbonates
《Chinese Journal of Chemistry》2024年第19期2357-2362,共6页Zhengnan Zhou Can Li Shengming Ma 
National Natural Science Foundation of China(No.21988101)is greatly appreciated.
Comprehensive Summary 2,3-Allenyl amines have shown wide applicability in biomedical and synthetic applications.Due to their enormous potential for applications,researchers have been dedicated to the development of me...
关键词：Pd catalysis 2 3-Allenyl amine Alk-2-yn-1 4-diol dicarbonate Organoboronic acid 1 2 3-Triene Methylene-π-allyl palladium species Regioselectivity CHEMOSELECTIVITY 
Accelerated heterogenous ring-opening polymerization towards well-defined helical poly(N-allyl alanine)with clickable side chains
《Science China Chemistry》2024年第6期2056-2062,共7页Anyao Ma Xin Wang Sunting Xuan Zhengbiao Zhang 
supported by the National Natural Science Foundation of China(22201197,21925107);the Collaborative Innovation Center of Suzhou Nano Science and Technology,National Key R&D Program of China(2022YFB3704900);the Natural Science Foundation of Jiangsu Province(BK20220507);the Natural Science Foundation of Jiangsu Higher Education Institutions(21KJB150035)。
Well-defined poly(N-allyl alanine)has been synthesized by heterogenous ring-opening polymerization(HROP)of less reactive N-allyl-alanine N-carboxyanhydride,using acetic acid as the catalyst and benzylamine as the init...
关键词：heterogenous ring-opening polymerization controlled polymerization stable helix clickable N-substituted polypeptide di-substituted polypeptoid 
Oxidative cyclization of allyl compounds and isocyanide: A facile entry to polysubstituted 2-cyanopyrroles
《Chinese Chemical Letters》2024年第4期330-335,共6页Yaping Zhang Wei Zhou Mingchun Gao Tianqi Liu Bingxin Liu Chang-Hua Ding Bin Xu 
the National Natural Science Foundation of China(Nos.22171178, 21871174, 22071143);Innovation Program of Shanghai Municipal Education Commission (No.2019–01–07–00–09-E00008) for financial support。
A facile Tf OH-catalyzed oxidative cyclization of allyl compounds and isocyanide has been developed with the assistance of DDQ, where isocyanide is used as the crucial "N" and "CN" sources. Highly functionalized 2-cya...
关键词：ISOCYANIDE Cyanopyrrole INSERTION Allyl compound Bronsted acid catalysis 
Copper-Catalyzed Highly Stereoselective Hydrodifluoroallylation of Cyclopropenes and Alkenyl Boronates with 3,3-Difluoroallyl Sulfonium Salts被引量：1
《Chinese Journal of Chemistry》2023年第24期3521-3527,共7页Xing Gao Xiaoxiao Ren Wei Deng Xingang Zhang 
Financial support for this work was provided by the National Key R&D Program of China(2021YFF0701700);the National Natural Science Foundation of China(21931013,22193072);the Science and Technology Committee of Shanghai Municipality(22JC1403500,21XD1404400).
Despite the paramount applications of organofluorine compounds in life and materials sciences,efficient strategies for stereoselectively constructing the C(sp^(3))-CF_(2)R bond at the stereogenic center remain limited...
关键词：Asymmetric catalysis Copper hydride Cross-coupling Synthetic methods Hydrofluoroalkylation Sulfonium salts 
Recent advances of Pd-π-allyl zwitterions in cycloaddition reactions被引量：1
《Chinese Chemical Letters》2023年第11期3-19,共17页Juan Du Yun-Fan Li Chang-Hua Ding 
the financial support from the National Natural Science Foundation of China(Nos.22071143 and 21772215);Start-up Funding for Scientific Research of Nanning Normal University(No.86612345);“BAGUI Scholar”Program of Guangxi Province of China。
Palladium-catalyzed cycloaddition reactions via Pd-π-allyl zwitterions have been established as significant synthetic transformations to enable numerous carbon-or heterocycles compounds that are key constituents of v...
关键词：Palladium CYCLOADDITION Pd-π-allyl zwitterions Asymmetric catalysis HETEROCYCLES 
Uncovering the solid-phase conversion mechanism via a new range of organosulfur polymer composite cathodes for lithium-sulfur batteries被引量：3
《Journal of Energy Chemistry》2023年第9期459-466,共8页Xiang Li Dezhong Liu Ziyi Cao Yaqi Liao Zexiao Cheng Jie Chen Kai Yuan Xing Lin Zhen Li Yunhui Huang Lixia Yuan 
supported by the National Science Foundation of China (22075091);the National Science Foundation of Hubei Province (2021CFA066)。
The sulfur cathodes operating via solid phase conversion of sulfur have natural advantages in suppressing polysulfide dissolution and lowering the electrolyte dosage,and thus realizing significant improvements in both...
关键词：Organosulfur polymer Lithium–sulfur batteries Allyl functional groups Reaction mechanism Solid–solid conversion 
Developments and applications of allyl-(aza)allyl coupling reactions
《Green Synthesis and Catalysis》2023年第3期190-205,共16页Leiyang Lv Huijun Qian 
supported by the National Natural Science Foundation of China(No.22201300);the Fundamental Research Funds for the Central Universities,and the Research Funds of Renmin University of China(No.21XNLG04).
We have summarized the developments and advancements of allyl-(aza)allyl coupling reactions in the past years.Since the first report in 1980,Pd-catalyzed allyl-allyl couplings have not drawn chemists'much attention fo...
关键词：ALLYLATION Pd catalysis CROSS-COUPLING C-C bond formation C-X bond formation 
1,1-Regioselective alkenylboration of styrenes enabled by palladium catalysis
《Chinese Chemical Letters》2023年第8期175-179,共5页Dong Wu Hailiang Pang Guoyin Yin 
This work was supported by grants from the National Natural Science Foundation of China(No.22122107);the Fundamental Research Funds for Central Universities(No.2042021kf0190).
Despite the 1,2-difunctionalization reactions of styrenes have been well developed, the 1,1-regioselective addition reaction remains challenging. We disclose herein a palladium-catalyzed, highly 1,1-regioselective alk...
关键词：STYRENES 1 1-Regioselectivity Chain-walking Palladium catalysis Allyl boronates 
Efficient and ecological leather processing: replacement of lime and sulphide with dispase assisted by 1-allyl-3-methylimidazolium chloride被引量：1
《Journal of Leather Science and Engineering》2022年第1期201-213,共13页Hui Liu Keyong Tang Xiumin Li Jie Liu Xuejing Zheng Ying Pei 
National Natural Science Foundation of China(No.51673177);National Key R&D Program of China(No.2017YFB0308500).
Leather is a collagen-based biomass prepared from raw skins or hides by a series of unit operations, in which the unhairing and fiber opening are extremely important operations. However, the conventional Na2S/Ca(OH)2 ...
关键词：1-Allyl-3-methylimidazolium chloride DISPASE Bovine hides Leather making Recycling Bioresource 
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