Financial supports were provided by the NSFC(22271249);the National Key R&D Program of China(2021YFF0701600 and 2021YFA1500200);the Fundamental Research Funds for the Central Universities(226-2022-00224 and 226-2024-00003);Zhejiang Provincial Natural Science Foundation of China(LDQ24B020001).
A mechanistically distinctive visible-light-promoted metal-free aerobic oxidation of alkenyl silanes with alcohols was disclosed to efficiently constructα-alkoxy ketones under mild conditions.The primary,secondary,an...
supported by Sichuan Science and Technology Program(No.2020YJ0221).
Cooperative NHC/photoredox catalysis has emerged as an important research field in recent years.Herein,this article describes the use of cesium salt derivatives of tert-alcohols as alkyl radical precursors in a three-...
support of the National Natural Science Foundation of China(grant no.21971071);the Natural Science Foundation of Guangdong Province(grant no.2021A1515010155).
Despite their interesting applications,direct and diverse syntheses of aryl-fused 2-alkyl cyclic amines still remain challenging.Here,the concept of incorporating a C–C coupling process into the N-heteroaryl reductio...
This work was supported by grants from the National Natural Science Foundation of China(No.22122107);the Fundamental Research Funds for Central Universities(No.2042021kf0190).
Despite the 1,2-difunctionalization reactions of styrenes have been well developed, the 1,1-regioselective addition reaction remains challenging. We disclose herein a palladium-catalyzed, highly 1,1-regioselective alk...
supported by the National Natural Science Foundation of China(22031008);Science Foundation of Wuhan(2020010601012192);The Program of Introducing Talents of Discipline to Universities of China(111 Program)is also appreciated.
A[4+2]annulation of two different styrenes to construct polysubstituted 1,2-dihydronaphthalenes was achieved.This transformation proceeded smoothly under electrochemical oxidative conditions without metal catalysts an...
support from the National Natural Science Foundation of China (No. 21472043)
α-(Trifluoromethyl)styrene and its derivatives have found wide applications in the fields of pharmaceuti-cals,agrochemicals,and advanced materials.They are also versatile trifluoromethyl-containing building blocks fo...
Financial support was provided by the the National Natural Science Foundation of China(nos.21822108,21822303,21801176,21772129,and 21772020);the Fok Ying Tung Education Foundation(no.161013);Sichuan Science and Technology Program(nos.2019YJ0379 and 20CXTD0112);the Fundamental Research Funds for the Central Universities.
Light-driven carbon dioxide(CO_(2))capture and utilization is one of the most fundamental reactions in Nature.Herein,we report the first visible-light-driven photocatalyst-free hydrocarboxylation of alkenes with CO_(2...
the National Natural Science Foundation of China(Nos.21825109,21821002,21732006);the National Basic Research Program of China(No.2016YFA0202900);the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB20000000);the Chinese Academy of Sciences Key Research Program of Frontier Sciences(No.QYZDB-SSW-SLH016);the K.C.Wong Education Foundation,and the Science and Technology Commission of Shanghai Municipality(No.17JC1401200)is gratefully acknowledged.
Main observation and conclusion Stereoselective isomerization of a-alkyl styrenes is accomplished using a new iron catalyst supported by phosphine-pyridine-oxazoline(PPO)ligand.The protocol provides an atom-efficient ...
support from the National Key Research and Development Program of China(No.2017YFD0200505)。
A novel and practical method for the synthesis of 3,5-bis(trifluoromethyl)-4,5-dihydro-1H-pyrazoles by [3+2] cycloaddition reactions of α-(trifluoromethyl)styrenes with 2,2,2-trifluorodiazoethane (CF3CHN2) has been d...
financially supported by the National Natural Science Foundation of China(Nos.21276041 and U1610104);by the Chinese Ministry of Education via the Program for New Century Excellent Talents in University(No. NCET-12-0079)
In this work, a spherical hollow mesoporous silica(SHMS) with high surface area(902 m^2/g) and large mesopore volume(1.31 cm^3/g) was prepared via a facile and scalable two-step soft-hard dual templateassisted sol-gel...