Evolution in the formation of graphene nanocapsules from coal tar pitch  

作　　者：D.M.Puente-Siller A.E.Garcia-Castillo J.A.Lopez-Corpus A.Perea-Garduno 

机构地区：[1]Department of Research and Development,Altos Hornos de Mexico,S.A.B.de C.V.Prolongacion Juarez,S/N,La Loma.25770 Monclova.Coahuila,Mexico

出　　处：《International Journal of Coal Science & Technology》2020年第4期816-824,共9页国际煤炭科学技术学报（英文）

基　　金：Altos Homos de Mexico,S.A.B.de C.V.:Funding for tests and analysis of synthesised materials.Consejo Nacional de Cienciay Tecnologia(CONACyT):Funding under“Proyecto FORDECYT273496”.

摘　　要：It has recently been reported that coal tar pitch(CTP)can be utilised as raw material for the production of graphene nanocapsules(GNCs)because it is formed by a great quantity of aromatic organic compounds(which promote the rearrangement of double bonds by a process of polymerisation).Due to the importance of graphene and the search for a non-expensive methodology to produce it,this work used CTP to synthesise GNCs using an in situ activation technique at low temperatures and evaluating the effect of the working temperature on the formation of such nanostructures.In other words,analysing the form of the particle as the temperature rises from 600 to 900℃.As result of the experimentation,powders were obtained and analysed by the techniques of X-Ray Diffraction,Raman Spectroscopy and Microscopy,employing Field Fmission Scanning Electron Microscopy by normal mode as well as by Scanning Transmission Electron Microscopy and a High-Resolution Scanning Electron Microscopy.The results show that working with temperatures between 800 and 850℃promotes the production of GNCs,considering that their size reduces as the working temperature rises.

关 键 词：Synthesis NANOCAPSULE GRAPHENE TAR AGGLOMERATION 

分 类 号：TQ127.11[化学工程—无机化工]