Radical Carbonylation under Low CO Pressure:Synthesis of Esters from Activated Alkylamines at Transition Metal-Free Conditions  被引量:3

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作  者:Fengqian Zhao Han-Jun Ai Xiao-Feng Wu 

机构地区:[1]Leibniz-Institut fur Katalyse e.V.an der Universitat Rostock,Albert-Einstein-Straße 29a,18059 Rostock,Germany [2]Dalian National Laboratory for Clean Energy,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,Liaoning,116023 China

出  处:《Chinese Journal of Chemistry》2021年第4期927-932,共6页中国化学(英文版)

摘  要:Main observation and conclusion High CO pressure(>40 bar)is usually needed in radical carbonylation reactions in the absence of metal catalyst.In this communication,we developed a transition-metal-free radical carbonylation of activated alkylamines with phenols and alcohols under low CO pressure(1-6 bar).Various esters were obtained in moderate to excellent yields under simple reaction conditions with good functional group compatibility.

关 键 词:CARBONYLATION RADICAL Ester ALKYLAMINE Katritzky salt 

分 类 号:O62[理学—有机化学]

 

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