Palladium-catalyzed enantioselective carbonylation reactions  

作　　者：Jin-Bao Peng Xin-Lian Liu Lin Li Xiao-Feng Wu 

机构地区：[1]School of Biotechnology and Health Sciences,Wuyi University,Jiangmen 529020,China [2]Dalian National Laboratory for Clean Energy,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Liaoning 116023,China [3]Leibniz-Institut für Katalyse e.V.,Albert-Einstein-Straße 29a,Rostock 18059,Germany

出　　处：《Science China Chemistry》2022年第3期441-461,共21页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(21801225);the Science Foundation for Young Teachers(2019td02);High-level Talent Research Start-up Project(2018TP018)of Wuyi University;the Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme(2019);the Department of Education of Guangdong Province(2020KCXTD036)。

摘　　要：Carbonylation,one of the most powerful approaches to the preparation of carbonylated compounds,has received significant attention from researchers active in various fields.Indeed,impressive progress has been made on this subject over the past few decades.Among the various types of carbonylation reactions,asymmetric carbonylation is a straightforward methodology for constructing chiral compounds.Although rhodium-catalyzed enantioselective hydroformylations have been discussed in several elegant reviews,a general review on palladium-catalyzed asymmetric carbonylations is still missing.In this review,we summarize and discuss recent achievements in palladium-catalyzed asymmetric carbonylation reactions.Notably,this review’s contents are categorized by reaction type.

关 键 词：palladium catalyst ENANTIOSELECTIVE CARBONYLATION CHIRAL 

分 类 号：O621.251[理学—有机化学]